Quantum state–resolved studies of chemisorption reactions

H Chadwick, RD Beck - Annual review of physical chemistry, 2017 - annualreviews.org
Chemical reactions at the gas–surface interface are ubiquitous in the chemical industry as
well as in nature. Investigating these processes at a microscopic, quantum state–resolved …

Atomic and molecular data for spacecraft re-entry plasmas

R Celiberto, I Armenise, M Cacciatore… - Plasma Sources …, 2016 - iopscience.iop.org
The modeling of atmospheric gas, interacting with the space vehicles in re-entry conditions
in planetary exploration missions, requires a large set of scattering data for all those …

Intake design for an atmosphere-breathing electric propulsion system (ABEP)

F Romano, J Espinosa-Orozco, M Pfeiffer, G Herdrich… - Acta Astronautica, 2021 - Elsevier
Challenging space missions include those at very low altitudes, where the atmosphere is
source of aerodynamic drag on the spacecraft. To extend the lifetime of such missions, an …

First Step of the Oxygen Reduction Reaction on Au(111): A Computational Study of O2 Adsorption at the Electrified Metal/Water Interface

AM Dudzinski, E Diesen, HH Heenen, VJ Bukas… - ACS …, 2023 - ACS Publications
Local field effects at the electrical double layer change the energies of reaction
intermediates in heterogeneous electrocatalysis. The resulting dependence on (absolute) …

Dynamics in reactions on metal surfaces: A theoretical perspective

B Jiang, H Guo - The Journal of Chemical Physics, 2019 - pubs.aip.org
Recent advances in theoretical characterization of reaction dynamics on metal surfaces are
reviewed. It is shown that the widely available density functional theory of metals and their …

Methane dissociation on Ni (111): A fifteen-dimensional potential energy surface using neural network method

X Shen, J Chen, Z Zhang, K Shao… - The Journal of Chemical …, 2015 - pubs.aip.org
In the present work, we develop a highly accurate, fifteen-dimensional potential energy
surface (PES) of CH 4 interacting on a rigid flat Ni (111) surface with the methodology of …

Efficient Water–Gas Shift Catalysts for H2O and CO Dissociation Using Cu–Ni Step Alloy Surfaces

S Roy, AK Tiwari - The Journal of Physical Chemistry C, 2021 - ACS Publications
H2O dissociation is the rate-limiting step for the water–gas shift (WGS) reaction. Density
functional theory (DFT) was used to study H2O and CO dissociation on a series of step (211) …

Nonthermalized precursor-mediated dissociative chemisorption at high catalysis temperatures

R Moiraghi, A Lozano, E Peterson, A Utz… - The Journal of …, 2020 - ACS Publications
Quasiclassical trajectory calculations and vibrational-state-selected beam-surface
measurements of CH4 chemisorption on Ir (111) reveal a nonthermal, hot-molecule …

Trends of Pd3Au(111) Alloy Surface Segregation in Oxygen, Carbon, and Nitrogen Environments

OV Vinogradova, K Reuter… - The Journal of Physical …, 2023 - ACS Publications
Catalytic properties of alloys are largely determined by the specific chemical composition at
the surface. Differences in composition between surface and bulk regions depend intricately …

Improved Theoretical Description of the H2 Chemisorption Dynamics on the W(100) Surface

LT Viaud, C Ibarguen Becerra, C Crespos… - The Journal of …, 2024 - ACS Publications
The dynamics of H2 chemisorption on W (100) is investigated by means of molecular
dynamics simulations performed on a new potential energy surface (PES) that includes …