Palladium-catalyzed transformations of alkyl C–H bonds

J He, M Wasa, KSL Chan, Q Shao, JQ Yu - Chemical Reviews, 2017‏ - ACS Publications
This Review summarizes the advancements in Pd-catalyzed C (sp3)–H activation via
various redox manifolds, including Pd (0)/Pd (II), Pd (II)/Pd (IV), and Pd (II)/Pd (0). While few …

The continuum of carbon–hydrogen (C–H) activation mechanisms and terminology

KM Altus, JA Love - Communications Chemistry, 2021‏ - nature.com
As a rapidly growing field across all areas of chemistry, CH activation/functionalisation is
being used to access a wide range of important molecular targets. Of particular interest is the …

Methane conversion into different hydrocarbons or oxygenates: current status and future perspectives in catalyst development and reactor operation

EV Kondratenko, T Peppel, D Seeburg… - Catalysis Science & …, 2017‏ - pubs.rsc.org
This Perspective highlights recent developments in methane conversion into different
hydrocarbons and oxygenates (methanol, its derivatives, and formaldehyde) with the …

Oxidative dehydrogenation of light alkanes with carbon dioxide

G Li, C Liu, X Cui, Y Yang, F Shi - Green Chemistry, 2021‏ - pubs.rsc.org
Oxidative dehydrogenation of light alkanes in the presence of carbon dioxide (CO2) via
heterogeneous catalysis is a sustainable approach. Compared with the strong O2 oxidant …

[HTML][HTML] Recent advances in catalysis involving bidentate N-heterocyclic carbene ligands

A Neshat, P Mastrorilli, A Mousavizadeh Mobarakeh - Molecules, 2021‏ - mdpi.com
Since the discovery of persistent carbenes by the isolation of 1, 3-di-l-adamantylimidazol-2-
ylidene by Arduengo and coworkers, we witnessed a fast growth in the design and …

Experiment and computation: a combined approach to study the reactivity of palladium complexes in oxidation states 0 to IV

KJ Bonney, F Schoenebeck - Chemical Society Reviews, 2014‏ - pubs.rsc.org
As the accuracy of computational chemistry increases, and the advent of more powerful
computers decreases the amount of time required to perform complex calculations, the use …

Recent progress in the development of catalysts for propane dehydrogenation in the presence of CO 2

KX Li, X Cai, HB Liu, XY Liu, YL Shan… - Reaction Chemistry & …, 2024‏ - pubs.rsc.org
Propane dehydrogenation (PDH) has become an important strategy to address the ever-
increasing global demand for propene. In this case, introducing CO2 as a soft oxidant for …

[كتاب][B] CH bond activation in organic synthesis

JJ Li - 2015‏ - books.google.com
CH activation involves any of a wide range of techniques, often using catalysts in which a
carbon to hydrogen covalent bond of an organic compound is cleaved to replace the …

Recent advances in bidentate bis (N-heterocyclic carbene) transition metal complexes and their applications in metal-mediated reactions

MG Gardiner, CC Ho - Coordination Chemistry Reviews, 2018‏ - Elsevier
The advanced development of NHC chemistry has lead to an extensive array of NHC ligand
classes varying in structural and electronic properties. Although monodentate NHC ligands …

Alkane C–H functionalization and oxidation with molecular oxygen

D Munz, T Strassner - Inorganic Chemistry, 2015‏ - ACS Publications
The application of environmentally benign, cheap, and economically viable oxidation
procedures is a key challenge of homogeneous, oxidative alkane functionalization. The …