Transition-Metal-Free C-Diarylations to Reach All-Carbon Quaternary Centers

S Mondal, B Gunschera, B Olofsson - JACS Au, 2024 - ACS Publications
Herein, we disclose a convenient protocol for the α-diarylation of carbon nucleophiles to
yield heavily functionalized quaternary products. Diaryliodonium salts are utilized to transfer …

A rapid pathway to molecular complexity: a palladium-catalyzed six-fold domino process to access polycyclic frameworks

K Goel, G Satyanarayana - Chemical Communications, 2025 - pubs.rsc.org
Herein, we present a hitherto unexplored efficient strategy for rapidly constructing
structurally constrained and intriguing polycyclic frameworks with two adjacent quaternary …

Creation of a Chiral All-Carbon Quaternary Center Induced by CF3 and CH3 Substituents via Cu-Catalyzed Asymmetric Conjugate Addition

T Yamamoto, M Asakura, K Yamanomoto… - Organic …, 2024 - ACS Publications
Cu-catalyzed asymmetric construction of a chiral quaternary center bearing CH3 and CF3
groups was achieved with high to excellent enantioselectivity using our originally developed …

Brønsted Acid-Mediated Selective α-Alkenylation of 3, 4-Dihydropyrans

N Chen, C Li, S Liao, J Chen, X Ma… - Organic Chemistry …, 2024 - pubs.rsc.org
A protocol for the synthesis of α-mono/disubstituted tetrahydropyrans (THPs) with vinyl cyclic
ethers and potassium trifluorob-orates was achieved in the presence of Brønsted acid and …

[PDF][PDF] Construction of All-Carbon Quaternary Center by Nhc-Catalyzed Heck-Type C–H Tertiary Alkylation

T Liu, P Yue, C Wang - Available at SSRN 5046717 - papers.ssrn.com
GSC template Page 1 Tetrahedron Chem Short Communication Construction of all-carbon
quaternary center by NHC-catalyzed Heck-type C–H tertiary alkylation Tinglan Liu a,# Pan …