Asymmetric diastereodivergent catalysis is a powerful strategy for accessing different
stereoisomers of a molecule, which are important in the discovery of biologically and …

Organocatalysis is widely recognized as a key synthetic methodology in organic chemistry. It
allows chemists to avoid the use of precious and (or) toxic metals by taking advantage of the …

Using chiral phosphoric acids as organocatalysts, a formal asymmetric (4+ 2) cycloaddition
of 3‐methylene isoindolinone and in situ‐generated ortho‐quinone methide substrates is …

Here we report Pd (0)-catalysed asymmetric inverse-electron-demand oxa-Diels–Alder
reactions between the carbonates of 4-hydroxy-2-cyclopentenones and α-cyano chalcones …

A new strategy for N-borylenamines by reaction of 2-alkynyl benzyl azides with B (C6F5) 3
was developed. This novel 1, 3-carboboration reaction proceeded via a 5-exo-dig …

Herein, we demonstrate an Oxa‐Diels‐Alder reaction of 3‐trifluoroacetyl‐4‐methyl‐quinolin‐
2 (1H)‐one with aldehydes in the presence of a base to engineer the functionalized pyrano …

This chapter covers the most recent advances on the synthesis of O-and S-6-membered
heterocycles reported during 2022. This personal overview is focused on the new …

Im Rahmen dieser Arbeit wurden drei Strategien zur Darstellung von zentralen
Strukturmotiven des Terpenoid-Naturstoffes Populusone untersucht. Dabei wurde zunächst …