Toward heterometallic single-molecule magnets: Synthetic strategy, structures and properties of 3d–4f discrete complexes
Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …
recent decades because of their potential advantages to create new single-molecule …
Magnetic interactions in molecules and highly correlated materials: physical content, analytical derivation, and rigorous extraction of magnetic Hamiltonians
Magnetism is a phenomenon that has always captured the imagination of humans. Its
discovery in the western world is attributed to the ancient Greek civilization. More than 2500 …
discovery in the western world is attributed to the ancient Greek civilization. More than 2500 …
Structure, Magnetism, and Theoretical Study of a Mixed-Valence CoII3CoIII4 Heptanuclear Wheel: Lack of SMM Behavior despite Negative Magnetic Anisotropy
A mixed-valence Co (II)/Co (III) heptanuclear wheel [CoII3CoIII4 (L) 6 (MeO) 6](LH2= 1, 1, 1-
trifluoro-7-hydroxy-4-methyl-5-aza-hept-3-en-2-one) has been synthesized and its crystal …
trifluoro-7-hydroxy-4-methyl-5-aza-hept-3-en-2-one) has been synthesized and its crystal …
Magnetic lanthanide–transition-metal organic–inorganic hybrid materials: From discrete clusters to extended frameworks
YG Huang, FL Jiang, MC Hong - Coordination Chemistry Reviews, 2009 - Elsevier
Magnetic lanthanide–transition-metal hybrid materials have enjoyed increasing attraction
because they not only provide examples for studying magnetic coupling involving …
because they not only provide examples for studying magnetic coupling involving …
Polyoxometalate-assisted synthesis of transition-metal cubane clusters as artificial mimics of the oxygen-evolving center of photosystem II
ZJ Liu, XL Wang, C Qin, ZM Zhang, YG Li… - Coordination chemistry …, 2016 - Elsevier
Abstract The {Mn 4 O 5 Ca} cluster of photosystem II is a well-known cubane-like transition-
metal (TM) cluster that plays important roles in solar energy conversion. The artificial …
metal (TM) cluster that plays important roles in solar energy conversion. The artificial …
3d–4f Clusters with large spin ground states and SMM behaviour
3d –4f Clusters with large spin ground states and SMM behaviour - Dalton Transactions (RSC
Publishing) DOI:10.1039/B927114G Royal Society of Chemistry View PDF VersionPrevious …
Publishing) DOI:10.1039/B927114G Royal Society of Chemistry View PDF VersionPrevious …
Recent advance in heterometallic nanomagnets based on TMxLn4− x cubane subunits
Abstract 3d-4f cubane-like complexes exhibit unique structural pattern, thus become a
fascinating subclass of 3d-4f complexes. In this review, we first present the structural …
fascinating subclass of 3d-4f complexes. In this review, we first present the structural …
A Tetranuclear, Macrocyclic 3d− 4f Complex Showing Single-Molecule Magnet Behavior
[CuII3TbIII (L Pr)(NO3) 2 (MeOH)(H2O) 2](NO3)· 3H2O is a rare example of a 3d− 4f single-
molecule magnet prepared using a macrocyclic ligand: at low T, it exhibits frequency …
molecule magnet prepared using a macrocyclic ligand: at low T, it exhibits frequency …
Slow magnetic relaxation and strong magnetic coupling in the nitroxyl radical complexes of lanthanide (iii) with diamagnetic ground state (Ln= Lu, Eu)
Radical lanthanide complexes are appealing platforms to investigate the possibility to
engineer relevant magnetic couplings between the two magnetic centers by exploiting the …
engineer relevant magnetic couplings between the two magnetic centers by exploiting the …
Hydroxide-Free Cubane-Shaped Tetranuclear [Ln4] Complexes
The reaction of the lanthanide (III) chloride salts [Gd (III), Tb (III), and Dy (III)] with a new
chelating, flexible, and sterically unencumbered multisite coordinating compartmental Schiff …
chelating, flexible, and sterically unencumbered multisite coordinating compartmental Schiff …