Electrochemistry of nanoparticles

SEF Kleijn, SCS Lai, MTM Koper… - Angewandte Chemie …, 2014 - Wiley Online Library
Metal nanoparticles (NPs) find widespread application as a result of their unique physical
and chemical properties. NPs have generated considerable interest in catalysis and …

Charge transport through molecular switches

SJ van der Molen, P Liljeroth - Journal of Physics: Condensed …, 2010 - iopscience.iop.org
We review the fascinating research on charge transport through switchable molecules. In the
past decade, detailed investigations have been performed on a great variety of molecular …

Anti-resonance features of destructive quantum interference in single-molecule thiophene junctions achieved by electrochemical gating

J Bai, A Daaoub, S Sangtarash, X Li, Y Tang, Q Zou… - Nature Materials, 2019 - nature.com
Controlling the electrical conductance and in particular the occurrence of quantum
interference in single-molecule junctions through gating effects has potential for the …

Single-molecule conductance of functionalized oligoynes: length dependence and junction evolution

P Moreno-García, M Gulcur, DZ Manrique… - Journal of the …, 2013 - ACS Publications
We report a combined experimental and theoretical investigation of the length dependence
and anchor group dependence of the electrical conductance of a series of oligoyne …

Correlations between molecular structure and single-junction conductance: a case study with oligo (phenylene-ethynylene)-type wires

V Kaliginedi, P Moreno-García… - Journal of the …, 2012 - ACS Publications
The charge transport characteristics of 11 tailor-made dithiol-terminated oligo (phenylene-
ethynylene)(OPE)-type molecules attached to two gold electrodes were studied at a …

Influence of conformation on conductance of biphenyl-dithiol single-molecule contacts

A Mishchenko, D Vonlanthen, V Meded, M Burkle… - Nano …, 2010 - ACS Publications
The conductance of a family of biphenyl-dithiol derivatives with conformationally fixed
torsion angle was measured using the scanning tunneling microscopy (STM)-break-junction …

[HTML][HTML] An MCBJ case study: The influence of π-conjugation on the single-molecule conductance at a solid/liquid interface

W Hong, H Valkenier, G Mészáros… - Beilstein journal of …, 2011 - beilstein-journals.org
Abstract π-Conjugation plays an important role in charge transport through single molecular
junctions. We describe in this paper the construction of a mechanically controlled break …

A Chemically Soldered Polyoxometalate Single‐Molecule Transistor

C Wu, X Qiao, CM Robertson, SJ Higgins… - Angewandte …, 2020 - Wiley Online Library
Polyoxometalates have been proposed in the literature as nanoelectronic components,
where they could offer key advantages with their structural versatility and rich …

Robust organic radical molecular junctions using acetylene terminated groups for C–Au bond formation

F Bejarano, IJ Olavarria-Contreras… - Journal of the …, 2018 - ACS Publications
Organic paramagnetic and electroactive molecules are attracting interest as core
components of molecular electronic and spintronic devices. Currently, further progress is …

Utilization of Electric Fields to Modulate Molecular Activities on the Nanoscale: From Physical Properties to Chemical Reactions

C Yang, Y Guo, H Zhang, X Guo - Chemical Reviews, 2024 - ACS Publications
As a primary energy source, electricity drives broad fields from everyday electronic circuits to
industrial chemical catalysis. From a chemistry viewpoint, studying electric field effects on …