The golden age of transfer hydrogenation
D Wang, D Astruc - Chemical reviews, 2015 - ACS Publications
Hydrogenation is one of the most fundamental transformations in organic synthesis, and its
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …
Asymmetric organocatalysis: an enabling technology for medicinal chemistry
B Han, XH He, YQ Liu, G He, C Peng… - Chemical Society Reviews, 2021 - pubs.rsc.org
The efficacy and synthetic versatility of asymmetric organocatalysis have contributed
enormously to the field of organic synthesis since the early 2000s. As asymmetric …
enormously to the field of organic synthesis since the early 2000s. As asymmetric …
Copper (I)-catalyzed asymmetric reactions involving radicals
QS Gu, ZL Li, XY Liu - Accounts of Chemical Research, 2019 - ACS Publications
Conspectus Asymmetric functionalization of alkyl radicals represents a robust yet
underdeveloped method for efficient construction and decoration of carbon skeletons in …
underdeveloped method for efficient construction and decoration of carbon skeletons in …
Quinone methides and indole imine methides as intermediates in enantioselective catalysis
X Li, Z Li, J Sun - Nature Synthesis, 2022 - nature.com
As a consequence of their propensity towards aromatization, quinone methides (QMs) and
indole imine methides (IIMs) are versatile intermediates in organic synthesis. Although QMs …
indole imine methides (IIMs) are versatile intermediates in organic synthesis. Although QMs …
Enantioselective benzylic C–H arylation via photoredox and nickel dual catalysis
X Cheng, H Lu, Z Lu - Nature Communications, 2019 - nature.com
The asymmetric cross-coupling reaction is developed as a straightforward strategy toward 1,
1-diaryl alkanes, which are a key skeleton in a series of natural products and bioactive …
1-diaryl alkanes, which are a key skeleton in a series of natural products and bioactive …
para‐Quinone Methides as Acceptors in 1,6‐Nucleophilic Conjugate Addition Reactions for the Synthesis of Structurally Diverse Molecules
para‐Quinone methides (p‐QMs) are naturally occurring molecules that have been finding
increasing synthetic applications in the last few years. The presence of two electronically …
increasing synthetic applications in the last few years. The presence of two electronically …
The emergence of quinone methides in asymmetric organocatalysis
Quinone methides (QMs) are highly reactive compounds that have been defined as “elusive”
intermediates, or even as a “synthetic enigma” in organic chemistry. Indeed, there were just …
intermediates, or even as a “synthetic enigma” in organic chemistry. Indeed, there were just …
Catalytic Asymmetric (4+3) Cyclizations of In Situ Generated ortho‐Quinone Methides with 2‐Indolylmethanols
M Sun, C Ma, SJ Zhou, SF Lou, J ** efficient methods for the synthesis of …
Emerging roles of in situ generated quinone methides in metal-free catalysis
ortho-Quinone methides have emerged recently as useful electrophiles in metal-free
catalysis. New strategies to access these species in situ that are compatible with …
catalysis. New strategies to access these species in situ that are compatible with …