Photocontrolled RAFT polymerization: past, present, and future
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …
Reversed controlled polymerization (RCP): depolymerization from well-defined polymers to monomers
Controlled polymerization methods are well-established synthetic protocols for the design
and preparation of polymeric materials with a high degree of precision over molar mass and …
and preparation of polymeric materials with a high degree of precision over molar mass and …
Atom transfer radical polymerization: a mechanistic perspective
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …
Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …
Amphiphilic block copolymers: their structures, and self-assembly to polymeric micelles and polymersomes as drug delivery vehicles
Self-assembly of amphiphilic block copolymers display a multiplicity of nanoscale periodic
patterns proposed as a dominant tool for the 'bottom-up'fabrication of nanomaterials with …
patterns proposed as a dominant tool for the 'bottom-up'fabrication of nanomaterials with …
Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …
recommended as reversible deactivation radical polymerization) is undoubtedly a …
Photocatalytic ATRP depolymerization: temporal control at low ppm of catalyst concentration
A photocatalytic ATRP depolymerization is introduced that significantly suppresses the
reaction temperature from 170 to 100° C while enabling temporal regulation. In the presence …
reaction temperature from 170 to 100° C while enabling temporal regulation. In the presence …
Reversing RAFT polymerization: near-quantitative monomer generation via a catalyst-free depolymerization approach
The ability to reverse controlled radical polymerization and regenerate the monomer would
be highly beneficial for both fundamental research and applications, yet this has remained …
be highly beneficial for both fundamental research and applications, yet this has remained …
Driving polymer brushes from synthesis to functioning
The great success of controlled radical polymerizations has encouraged researchers to
develop more facile and robust approaches for surface‐initiated polymerizations (SIPs) to …
develop more facile and robust approaches for surface‐initiated polymerizations (SIPs) to …
Fast bulk depolymerization of polymethacrylates by ATRP
Fast bulk depolymerization of poly (n-butyl methacrylate) and poly (methyl methacrylate),
prepared by atom transfer radical polymerization (ATRP), is reported in the temperature …
prepared by atom transfer radical polymerization (ATRP), is reported in the temperature …