Rise of conjugated poly-ynes and poly (metalla-ynes): from design through synthesis to structure–property relationships and applications
Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …
with potential application in various domains of science. The key factors responsible for the …
An update on the use of sulfinate derivatives as versatile coupling partners in organic chemistry
J Aziz, A Hamze - Organic & Biomolecular Chemistry, 2020 - pubs.rsc.org
The use of sulfinic acids and their salts continues to be extensively developed in organic
chemistry. This is attributable to their dual capacity for acting as nucleophilic or electrophilic …
chemistry. This is attributable to their dual capacity for acting as nucleophilic or electrophilic …
A metal-free route to alkynyl sulfones under photoinduced conditions with the insertion of sulfur dioxide
X Gong, M Yang, JB Liu, FS He, X Fan, J Wu - Green Chemistry, 2020 - pubs.rsc.org
A metal-free route to alkynyl sulfones under photoinduced conditions is accomplished,
starting from 4-alkyl Hantzsch esters, sulfur dioxide, and alkynyl bromides under visible light …
starting from 4-alkyl Hantzsch esters, sulfur dioxide, and alkynyl bromides under visible light …
C2-selective direct alkynylation of indoles
The first C2-selective alkynylation of indoles using the hypervalent iodine reagent
triisopropylsilylethynyl-1, 2-benziodoxol-3 (1 H)-one (TIPS-EBX) with Pd (II) as a catalyst is …
triisopropylsilylethynyl-1, 2-benziodoxol-3 (1 H)-one (TIPS-EBX) with Pd (II) as a catalyst is …
[LIBRO][B] Lithium compounds in organic synthesis: from fundamentals to applications
R Luisi, V Capriati - 2014 - books.google.com
This unique book covers fundamentals of organolithium compounds and gives a
comprehensive overview of the latest synthetic advances and developments in the field. Part …
comprehensive overview of the latest synthetic advances and developments in the field. Part …
One-pot, three-component arylalkynyl sulfone synthesis
CC Chen, J Waser - Organic letters, 2015 - ACS Publications
A one-pot three-component protocol for the preparation of arylsulfonyl alkynes through the
reaction of ethynyl-benziodoxolone (EBX) reagents, DABSO (DABCO· SO2), and either …
reaction of ethynyl-benziodoxolone (EBX) reagents, DABSO (DABCO· SO2), and either …
Nature of the nucleophilic oxygenation reagent is key to acid-free gold-catalyzed conversion of terminal and internal alkynes to 1, 2-dicarbonyls
AY Dubovtsev, NV Shcherbakov… - The Journal of …, 2019 - ACS Publications
2, 3-Dichloropyridine N-oxide, a novel oxygen transfer reagent, allows the conductance of
the gold (I)-catalyzed oxidation of alkynes to 1, 2-dicarbonyls in the absence of any acid …
the gold (I)-catalyzed oxidation of alkynes to 1, 2-dicarbonyls in the absence of any acid …
Electrochemical Sulfonylation of Alkynes with Sulfonyl Hydrazides: A Metal‐and Oxidant‐Free Protocol for the Synthesis of Alkynyl Sulfones
ZY Mo, YZ Zhang, GB Huang, XY Wang… - Advanced Synthesis …, 2020 - Wiley Online Library
Herein, an electrochemical oxidative cross‐coupling reaction between terminal alkynes and
sulfonylhydrazides has been developed. Tetrabutylammonium iodide is used as the …
sulfonylhydrazides has been developed. Tetrabutylammonium iodide is used as the …
Iodine-catalyzed sulfonylation of arylacetylenic acids and arylacetylenes with sodium sulfinates: synthesis of arylacetylenic sulfones
J Meesin, P Katrun, C Pareseecharoen… - The Journal of …, 2016 - ACS Publications
A highly efficient and generally applicable iodine-catalyzed reaction of arylacetylenic acids
and arylacetylenes with sodium sulfinates for the synthesis of arylacetylenic sulfones was …
and arylacetylenes with sodium sulfinates for the synthesis of arylacetylenic sulfones was …
Photoinduced synthesis of alkylalkynyl sulfones through a reaction of potassium alkyltrifluoroborates, sulfur dioxide, and alkynyl bromides
X Gong, M Yang, JB Liu, FS He, J Wu - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
A photoinduced reaction of potassium alkyltrifluoroborates, sulfur dioxide, and alkynyl
bromides under visible light irradiation at room temperature is developed, giving rise to …
bromides under visible light irradiation at room temperature is developed, giving rise to …