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Photoactive copper complexes: properties and applications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …
recently and have become among the most active areas of chemical research, notably due …
A new era of LMCT: leveraging ligand-to-metal charge transfer excited states for photochemical reactions
Ligand-to-metal charge transfer (LMCT) excited states are capable of undergoing a wide
array of photochemical reactions, yet receive minimal attention compared to other charge …
array of photochemical reactions, yet receive minimal attention compared to other charge …
Photo-and electro-chemical strategies for the activations of strong chemical bonds
The employment of light and/or electricity–alternatively to conventional thermal energy–
unlocks new reactivity paradigms as tools for chemical substrate activations. This leads to …
unlocks new reactivity paradigms as tools for chemical substrate activations. This leads to …
Photoelectrochemical asymmetric catalysis enables direct and enantioselective decarboxylative cyanation
The development of efficient and sustainable methods for decarboxylative transformations is
of great importance due to the ease of availability and nontoxicity of carboxylic acids …
of great importance due to the ease of availability and nontoxicity of carboxylic acids …
Photocatalytic C–H activation and the subtle role of chlorine radical complexation in reactivity
The functionalization of methane, ethane, and other alkanes derived from fossil fuels is a
central goal in the chemical enterprise. Recently, a photocatalytic system comprising …
central goal in the chemical enterprise. Recently, a photocatalytic system comprising …
Visible‐light‐induced homolysis of earth‐abundant metal‐substrate complexes: A complementary activation strategy in photoredox catalysis
The mainstream applications of visible‐light photoredox catalysis predominately involve
outer‐sphere single‐electron transfer (SET) or energy transfer (EnT) processes of precious …
outer‐sphere single‐electron transfer (SET) or energy transfer (EnT) processes of precious …
Unveiling extreme photoreduction potentials of donor–acceptor cyanoarenes to access aryl radicals from aryl chlorides
Since the seminal work of Zhang in 2016, donor–acceptor cyanoarene-based fluorophores,
such as 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN), have been widely …
such as 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN), have been widely …
A toolbox approach to construct broadly applicable metal-free catalysts for photoredox chemistry: deliberate tuning of redox potentials and importance of halogens in …
E Speckmeier, TG Fischer, K Zeitler - Journal of the American …, 2018 - ACS Publications
The targeted choice of specific photocatalysts has been shown to play a critical role for the
successful realization of challenging photoredox catalytic transformations. Herein, we …
successful realization of challenging photoredox catalytic transformations. Herein, we …
Photoinduced borylation for the synthesis of organoboron compounds: focus review
Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …
transformations. The development of practical and convenient ways to synthesize boronate …
Multi‐photon excitation in photoredox catalysis: concepts, applications, methods
The energy of visible photons and the accessible redox potentials of common photocatalysts
set thermodynamic limits to photochemical reactions that can be driven by traditional visible …
set thermodynamic limits to photochemical reactions that can be driven by traditional visible …