Control, modulation, and analytical descriptions of vibrational strong coupling

BS Simpkins, AD Dunkelberger, I Vurgaftman - Chemical Reviews, 2023 - ACS Publications
Here, we review the design of optical cavities, transient and modulated responses, and
theoretical models relevant to vibrational strong coupling (VSC). While planar Fabry–Perot …

Molecular polaritons for chemistry, photonics and quantum technologies

B **ang, W **ong - Chemical Reviews, 2024 - ACS Publications
Molecular polaritons are quasiparticles resulting from the hybridization between molecular
and photonic modes. These composite entities, bearing characteristics inherited from both …

Modification of ground-state chemical reactivity via light–matter coherence in infrared cavities

W Ahn, JF Triana, F Recabal, F Herrera, BS Simpkins - Science, 2023 - science.org
Reaction-rate modifications for chemical processes due to strong coupling between reactant
molecular vibrations and the cavity vacuum have been reported; however, no currently …

Molecular polaritonics: Chemical dynamics under strong light–matter coupling

TE Li, B Cui, JE Subotnik, A Nitzan - Annual review of physical …, 2022 - annualreviews.org
Chemical manifestations of strong light–matter coupling have recently been a subject of
intense experimental and theoretical studies. Here we review the present status of this field …

Vibration-cavity polariton chemistry and dynamics

AD Dunkelberger, BS Simpkins… - Annual review of …, 2022 - annualreviews.org
Molecular polaritons result from light-matter coupling between optical resonances and
molecular electronic or vibrational transitions. When the coupling is strong enough, new …

[HTML][HTML] Molecular polaritons for controlling chemistry with quantum optics

F Herrera, J Owrutsky - The Journal of chemical physics, 2020 - pubs.aip.org
This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic
physical principles and consequences of strong light–matter coupling common to molecular …

Mode-Specific Chemistry through Vibrational Strong Coupling (or A Wish Come True)

BS Simpkins, AD Dunkelberger… - The Journal of Physical …, 2021 - ACS Publications
Vibrational strong coupling offers newfound potential to affect chemical processes and
represents a wholly new approach to catalysis. While this presents extraordinary …

Linear response of molecular polaritons

J Yuen-Zhou, A Koner - The Journal of Chemical Physics, 2024 - pubs.aip.org
In this article, we show that the collective light–matter strong coupling regime where N
molecular emitters couple to the photon mode of an optical cavity can be mapped to a …

Excited-state vibration-polariton transitions and dynamics in nitroprusside

AB Grafton, AD Dunkelberger, BS Simpkins… - Nature …, 2021 - nature.com
Strong cavity coupling to molecular vibrations creates vibration-polaritons capable of
modifying chemical reaction kinetics, product branching ratios, and charge transfer …

Molecular vibrational polariton: Its dynamics and potentials in novel chemistry and quantum technology

B **ang, W **ong - The Journal of Chemical Physics, 2021 - pubs.aip.org
Molecular vibrational polaritons, a hybridized quasiparticle formed by the strong coupling
between molecular vibrational modes and photon cavity modes, have attracted tremendous …