Atomically precise colloidal metal nanoclusters and nanoparticles: fundamentals and opportunities
Colloidal nanoparticles are being intensely pursued in current nanoscience research.
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …
Nanochemists are often frustrated by the well-known fact that no two nanoparticles are the …
A review of state of the art in phosphine ligated gold clusters and application in catalysis
Atomically precise gold clusters are highly desirable due to their well‐defined structure
which allows the study of structure–property relationships. In addition, they have potential in …
which allows the study of structure–property relationships. In addition, they have potential in …
Sulfide boosting near-unity photoluminescence quantum yield of silver nanocluster
SS Zhang, S Havenridge, C Zhang… - Journal of the …, 2022 - ACS Publications
Silver nanoclusters have emerged as promising candidates for optoelectronic applications,
but their room-temperature photoluminescence quantum yield (PLQY) is far from ideal to …
but their room-temperature photoluminescence quantum yield (PLQY) is far from ideal to …
Toward controlled syntheses of diphosphine-protected homochiral gold nanoclusters through precursor engineering
WD Si, YZ Li, SS Zhang, S Wang, L Feng, ZY Gao… - ACS …, 2021 - ACS Publications
Controllable syntheses of Au nanoclusters (NCs) with different nuclearities are of great
significance due to the kernel-dependent physicochemical properties. Herein, two pairs of …
significance due to the kernel-dependent physicochemical properties. Herein, two pairs of …
On‐line reaction monitoring and mechanistic studies by mass spectrometry: Negishi cross‐coupling, hydrogenolysis, and reductive amination
Reaction monitoring using inductive ESI mass spectrometry allows chemical reactions to be
tracked in real time, including air‐and moisture‐sensitive as well as heterogeneous …
tracked in real time, including air‐and moisture‐sensitive as well as heterogeneous …
Octagold selenido nanoclusters: Significance of surface ligands on tuning geometric and electronic structure of Au8Se2 kernel
S Zhang, Y Li, L Feng, Q Xue, Z Gao, C Tung, D Sun - Nano Research, 2021 - Springer
Two diphosphine-protected superatom gold selenido nanoclusters,[Au8Se2 (dppm) 4]
2+(SD/Au8a, dppm= Ph2PCH2PPh2) and [Au8Se2 (dppe) 4] 2+(SD/Au8b, dppe= Ph2P …
2+(SD/Au8a, dppm= Ph2PCH2PPh2) and [Au8Se2 (dppe) 4] 2+(SD/Au8b, dppe= Ph2P …
Understanding ligand effects in gold clusters using mass spectrometry
This review summarizes recent research on the influence of phosphine ligands on the size,
stability, and reactivity of gold clusters synthesized in solution. Sub-nanometer clusters …
stability, and reactivity of gold clusters synthesized in solution. Sub-nanometer clusters …
Chiral noble metal nanoparticles and nanostructures
The origins of chirality and chiroptical properties in ligand‐protected gold and silver
nanoparticles (NPs) are considered herein. Current conceptual models including the chiral …
nanoparticles (NPs) are considered herein. Current conceptual models including the chiral …
Benchmark Models for Elucidating Ligand Effects: Thiols Ligated Isostructural Cu6 Nanoclusters
L Zhang, M Guo, J Zhou, C Fang, X Sun - Small, 2023 - Wiley Online Library
Atomically precise copper nanoclusters (Cu NCs) have attracted tremendous attention for
their huge potential in many applications. However, the uncertainty of the growth mechanism …
their huge potential in many applications. However, the uncertainty of the growth mechanism …
Ligand induced structural isomerism in phosphine coordinated gold clusters revealed by ion mobility mass spectrometry
Structural isomerism in ligated gold clusters is revealed using electrospray ionization ion
mobility spectrometry mass spectrometry. Phosphine ligated Au8 clusters are shown to …
mobility spectrometry mass spectrometry. Phosphine ligated Au8 clusters are shown to …