Applications of chiroptical spectroscopy to coordination compounds

T Wu, XZ You, P Bouř - Coordination Chemistry Reviews, 2015 - Elsevier
Chiroptical methods represent indispensable tools for structural studies of chiral
coordination compounds. Numerous applications in asymmetric catalysis, chiral recognition …

Block copolymer enabled synthesis and assembly of chiral metal oxide nanoparticle

M Kim, J Kim, HJ Lee, H Kim, KT Nam, DH Kim - ACS nano, 2023 - ACS Publications
Chiral metal oxide nanostructures have received tremendous attention in nanotechnological
applications owing to their intriguing chiroptical and magnetic properties. Current synthetic …

VCD studies on chiral characters of metal complex oligomers

H Sato, A Yamagishi - International Journal of Molecular Sciences, 2013 - mdpi.com
The present article reviews the results on the application of vibrational circular dichroism
(VCD) spectroscopy to the study of stereochemical properties of chiral metal complexes in …

Solvation-induced helicity inversion of pseudotetrahedral chiral copper (II) complexes

AC Chamayou, G Makhloufi, LA Nafie… - Inorganic …, 2015 - ACS Publications
The helicity of four-coordinated nonplanar complexes is strongly correlated to the chirality of
the ligand. However, the stereochemical induction of either the Δ-or the Λ-configuration at …

Three properties in one coordination complex: chirality, spin crossover, and dielectric switching

J Ru, F Yu, PP Shi, CQ Jiao, CH Li… - European Journal of …, 2017 - Wiley Online Library
In the search for multifunctional molecular materials, we designed an enantiopure pair of
FeII complexes with chiral, chelating (R)/(S)‐4, 5‐pinenepyridyl‐2‐pyrazine ligands …

Vapor-induced chiroptical switching in chiral cyclometalated platinum (II) complexes with pinene functionalized C^ N^ N ligands

XP Zhang, T Wu, J Liu, JX Zhang, CH Li… - Journal of Materials …, 2014 - pubs.rsc.org
A new couple of enantiomeric chiral cyclometalated platinum (II) complexes Pt (La)(CC–
Ph)(1a) and Pt (Lb)(CC–Ph)(1b)(La=(−)-4, 5-pinene-6′-phenyl-2, 2′-bipyridine, Lb=(+)-4 …

Nontrivial spectral band progressions in electronic circular dichroism spectra of carbohelicenes revealed by linear response calculations

M Brand, P Norman - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
We demonstrate that contemporary computational resources allow for accurate theoretical
studies of systems matching recent advances in experimental helicene chemistry …

Exciton coupling analysis and enolization monitoring by vibrational circular dichroism spectra of camphor diketones

T Wu, X You - The Journal of Physical Chemistry A, 2012 - ACS Publications
The keto–enol tautomerization of (1 R, 3 R, 4 R)-(+)-3-benzoylcamphor in solution was
traced by the infrared (IR) and vibrational circular dichroism (VCD) spectra, reflecting the …

Comparison of the electronic and vibrational optical activity of a europium (III) complex

T Wu, J Hudecová, XZ You… - … –A European Journal, 2015 - Wiley Online Library
The geometry and the electronic structure of chiral lanthanide (III) complexes are
traditionally probed by electronic methods, such as circularly polarised luminescence (CPL) …

Novel redox responsive chiral cyclometalated platinum (ii) complexes with pinene functionalized C^ N^ N ligands

XP Zhang, FQ Liu, JC Lai, CH Li, AM Li… - New Journal of …, 2016 - pubs.rsc.org
By oxidation of a couple of chiral cyclometalated platinum (II) complexes, Pt (La)(CC–
Ph)(1a) and Pt (Lb)(CC–Ph)(1b)(La=(−)-4, 5-pinene-6′-phenyl-2, 2′-bipyridine and …