Supported catalysis in continuous‐flow microreactors

R Munirathinam, J Huskens… - Advanced synthesis & …, 2015 - Wiley Online Library
This review surveys the recent developments to perform heterogeneous catalysis in
continuous‐flow microreactors. Three different types, namely,(i) packed‐bed,(ii) monolithic …

Polymer brushes here, there, and everywhere: Recent advances in their practical applications and emerging opportunities in multiple research fields

O Azzaroni - Journal of Polymer Science Part A: Polymer …, 2012 - Wiley Online Library
Bottom‐up surface processing with well‐defined polymeric structures becomes increasingly
important in many current technologies. Polymer brushes, that is, assemblies of …

Opportunities, challenges, and pitfalls in making, characterizing, and understanding polymer brushes

CW Pester, HA Klok, EM Benetti - Macromolecules, 2023 - ACS Publications
Polymer brushes have been theoretically described, their behavior under diverse conditions
has been modeled, and their preparation via surface-initiated polymerizations (SIPs) has …

Different EDC/NHS activation mechanisms between PAA and PMAA brushes and the following amidation reactions

C Wang, Q Yan, HB Liu, XH Zhou, SJ **ao - Langmuir, 2011 - ACS Publications
Infrared spectroscopy was applied to investigate the well-known EDC/NHS (N-ethyl-N′-(3-
(dimethylamino) propyl) carbodiimide/N-hydroxysuccinimide) activation details of poly …

Surface-initiated photoinduced ATRP: Mechanism, oxygen tolerance, and temporal control during the synthesis of polymer brushes

W Yan, S Dadashi-Silab, K Matyjaszewski… - …, 2020 - ACS Publications
Surface-initiated, photoinduced atom transfer radical polymerization (SI-photoATRP)
enables the controlled and rapid synthesis of compositionally diverse polymer brushes over …

Biomolecule-functionalized polymer brushes

H Jiang, FJ Xu - Chemical Society Reviews, 2013 - pubs.rsc.org
Functional polymer brushes have been utilized extensively for the immobilization of
biomolecules, which is of crucial importance for the development of biosensors and …

Controlled decoration of the surface with macromolecules: polymerization on a self-assembled monolayer (SAM)

P Murugan, M Krishnamurthy, SN Jaisankar… - Chemical Society …, 2015 - pubs.rsc.org
Polymer functionalized surfaces are important components of various sensors, solar cells
and molecular electronic devices. In this context, the use of self-assembled monolayer …

Growing Polymer Brushes from a Variety of Substrates under Ambient Conditions by Cu0-Mediated Surface-Initiated ATRP

W Yan, M Fantin, S Ramakrishna… - … applied materials & …, 2019 - ACS Publications
Cu0-mediated surface-initiated atom transfer radical polymerization (Cu0 SI-ATRP) is a
highly versatile, oxygen-tolerant, and extremely controlled polymer-grafting technique that …

[PDF][PDF] Safe Use of a Toxic Compound: Heterogeneous OsO4 Catalysis in a Nanobrush Polymer Microreactor.

KC Basavaraju, S Sharma, RA Maurya… - Angewandte Chemie, 2013 - academia.edu
Some catalysts are toxic and volatile, this volatility allows permeation of the toxin throughout
its environment, and yet these catalysts are, in many cases, essential for organic synthesis …

Loops and cycles at surfaces: The unique properties of topological polymer brushes

EM Benetti, M Divandari… - … A European Journal, 2017 - Wiley Online Library
Grafting synthetic polymers to inorganic and organic surfaces to yield polymer “brushes” has
represented a revolution in many fields of materials science. Polymer brushes provide …