[HTML][HTML] Spin state switching in iron coordination compounds
P Gütlich, AB Gaspar, Y Garcia - Beilstein journal of organic …, 2013 - beilstein-journals.org
The article deals with coordination compounds of iron (II) that may exhibit thermally induced
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …
spin transition, known as spin crossover, depending on the nature of the coordinating ligand …
Structure: function relationships in molecular spin-crossover complexes
MA Halcrow - Chemical Society Reviews, 2011 - pubs.rsc.org
Spin-crossover compounds are becoming increasingly popular for device and sensor
applications, and in soft materials, that make use of their switchable colour, paramagnetism …
applications, and in soft materials, that make use of their switchable colour, paramagnetism …
Spin crossover with thermal hysteresis: practicalities and lessons learnt
S Brooker - Chemical Society Reviews, 2015 - pubs.rsc.org
The observation of spin crossover with thermal hysteresis loops of more than a few Kelvin
remains relatively uncommon and unpredictable, so is a relatively underdeveloped, but …
remains relatively uncommon and unpredictable, so is a relatively underdeveloped, but …
Spin crossover in discrete polynuclear iron (II) complexes
Iron (II) spin crossover (SCO) materials have been widely studied as molecular switches with
a wide variety of potential applications, including as displays, sensors, actuators or memory …
a wide variety of potential applications, including as displays, sensors, actuators or memory …
Vapochromic effect in switchable molecular-based spin crossover compounds
E Resines-Urien, E Fernandez-Bartolome… - Chemical Society …, 2023 - pubs.rsc.org
Coordination complexes based on transition metal ions displaying [Ar] 3d4–3d7 electronic
configurations can undergo the likely most spectacular switchable phenomena found in …
configurations can undergo the likely most spectacular switchable phenomena found in …
Spin-crossover iron (II) coordination polymer with fluorescent properties: Correlation between emission properties and spin state
A spin-crossover coordination polymer [Fe (L1)(bipy)] n (where L= a N2O22–coordinating
Schiff base-like ligand bearing a phenazine fluorophore and bipy= 4, 4′-bipyridine) was …
Schiff base-like ligand bearing a phenazine fluorophore and bipy= 4, 4′-bipyridine) was …
An iron (II) spin-crossover complex with a 70 K wide thermal hysteresis loop
B Weber, W Bauer, J Obel - Angewandte Chemie International …, 2008 - eref.uni-bayreuth.de
Going loopy: A new iron (II) spin-crossover complex displays a 70 K wide thermal hysteresis
loop, which can be explained by an intermolecular 2D network of hydrogen bonds. This is …
loop, which can be explained by an intermolecular 2D network of hydrogen bonds. This is …
Remarkable scan rate dependence for a highly constrained dinuclear iron (II) spin crossover complex with a wide thermal hysteresis loop
The abrupt [HS-HS]↔ localized [HS-LS] spin crossovers of a new triazole-based diiron (II)
complex result in a record-equaling thermal hysteresis loop width for a dinuclear complex (Δ …
complex result in a record-equaling thermal hysteresis loop width for a dinuclear complex (Δ …
Asymmetric design of spin-crossover complexes to increase the volatility for surface deposition
A mononuclear complex [Fe (t Bu2qsal) 2] has been obtained by a reaction between an Fe
(II) precursor salt and a tridentate ligand 2, 4-di (tert-butyl)-6-((quinoline-8-ylimino) methyl) …
(II) precursor salt and a tridentate ligand 2, 4-di (tert-butyl)-6-((quinoline-8-ylimino) methyl) …
A Trinuclear Defect‐Grid Iron (II) Spin Crossover Complex with a Large Hysteresis Loop that is Readily Silenced by Solvent Vapor
M Steinert, B Schneider, S Dechert… - Angewandte …, 2014 - Wiley Online Library
A new type of [2× 2] matrix‐like complexes with one vertex devoid of a metal ion has been
selectively synthesized. The defect‐grid triiron (II) complex exhibits a sharp and complete …
selectively synthesized. The defect‐grid triiron (II) complex exhibits a sharp and complete …