Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

Conspectus Transition metal-catalyzed carbonylation reactions represent a direct and atom-
economical approach to introduce oxygen functionality into organic compounds, with CO …

The development of transition metal (TM) catalysis for organic synthesis under visible light
without recourse to typical photoredox catalysts has become a rapidly growing area of …

Conspectus Numerous methods for transition metal catalyzed carbonylation reactions have
been established. Examples that start from aryl, vinyl, allyl, and benzyl halides to give the …

The use of first row transition metal complexes is one of the mainstreams in modern
homogeneous catalysis. The case of manganese is peculiar in that catalytic applications of …

Transition metal catalysts are formidable tools towards greener chemistry, allowing for low-
waste, energy-efficient, and selective reactions. And transition metal-catalysed carbonylation …

We describe here the development of a visible light driven nickel carbonylation catalyst. The
combination of the large bite‐angle Xantphos ligand with nickel (0) generates a catalyst …

In the last few decades, photocatalytic radical carbonylation strategies have received
considerable attention as they are becoming a formidable tool in the toolbox of organic …

Alkyl carboxylic acids as well as primary amines are ubiquitous in all facets of biological
science, pharmaceutical science, chemical science and materials science. By chemical …

The first radical alkoxycarboxylation of aryldiazonium salts using CO gas through visible‐
light‐induced photoredox catalysis (16 W blue LEDs) has been developed. This reaction is …