Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

Transition metal catalysis is of utmost importance for the development of sustainable
processes in academia and industry. The activity and selectivity of metal complexes are …

In this (tutorial overview) perspective we highlight the use of “redox non-innocent” ligands in
catalysis. Two main types of reactivity in which the redox non-innocent ligand is involved can …

Enantioselective transition metal catalysis is an area very much at the forefront of
contemporary synthetic research. The development of processes that enable the efficient …

Cyclopropanes bearing contiguous all-carbon quaternary centers continue to attract
attention due to their bioactivities. However, methods to obtain cyclopropanes with …

A concept for intermolecular C–N cross-coupling amination has been discovered using
tetrazoles and aromatic and aliphatic azides with boronic acids under iron-catalyzed …

This review highlights and summarizes various optically active porphyrin and
phthalocyanine molecules prepared using a wide range of structural modification methods …

Recently, with the boosted development of radical chemistry, enantioselective
functionalization of C (sp 3)–H bonds via a radical pathway has witnessed a renaissance. In …

Organocobalt (III) complexes (R-CoIII), defined as cobalt complexes featuring a carbon–
cobalt bond, are largely used to produce carbon-centered radicals by homolytic cleavage of …

Cyclopropanes are among the most important structural units in natural products,
pharmaceuticals, and agrochemicals. Herein, we report a manganese-catalyzed …