Azo-oximate metal-carbonyl to metallocarboxylic acid via the intermediate Ir (III) radical congener: quest for co-ligand driven stability of open-and closed-shell …

S Dinda, S Pramanik, J Basu, SC Patra… - Dalton …, 2022 - pubs.rsc.org
The redox non-innocent behavior of the diaryl-azo-oxime ligand LNOH1 has been
accentuated via the synthesis of metastable anion radical complexes of type trans-[Ir …

Halogen Bonding in Stereoselective Metal Chloride (M–Cl) Bond Activation and Transformation to Metal Triiodide (M–I3)

S Dinda, D Jana, RM Gomila, A Frontera… - Crystal Growth & …, 2024 - ACS Publications
The isolation of isomeric complexes trans-[RuIILPyHPQ (CO)(PPh3) Cl] 2 and cis-
[RuIILPyHPQ (CO)(PPh3) Cl] 3,(Cl and PPh3 are trans in 2 and they are cis in 3 …

Role of ligand disposition and oxime… oximato hydrogen bonding upon redox non-innocent character of rhodium (III) phenylazooximates

S Naskar, S Halder, G Kanrar, D Jana, S Dinda… - Polyhedron, 2023 - Elsevier
The diaryl-azo-oxime ligands HL, 1 undergoes oxidative coordination reaction with
Wilkinson's catalyst to form two isomeric complexes of type cis-[Rh III L 2 Cl (PPh 3)], 2a (Cl …