Electronic defects in metal oxide photocatalysts

E Pastor, M Sachs, S Selim, JR Durrant… - Nature Reviews …, 2022 - nature.com
A deep understanding of defects is essential for the optimization of materials for solar energy
conversion. This is particularly true for metal oxide photo (electro) catalysts, which typically …

Charge carrier dynamics and reaction intermediates in heterogeneous photocatalysis by time-resolved spectroscopies

J Ma, TJ Miao, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Sunlight as the most abundant renewable energy holds the promise to make our society
sustainable. However, due to its low power density and intermittence, efficient conversion …

Hole utilization in solar hydrogen production

MZ Rahman, T Edvinsson, J Gascon - Nature Reviews Chemistry, 2022 - nature.com
In photochemical production of hydrogen from water, the hole-mediated oxidation reaction is
the rate-determining step. A poor solar-to-hydrogen efficiency is usually related to a …

Impact of Oxygen Vacancy Occupancy on Charge Carrier Dynamics in BiVO4 Photoanodes

S Selim, E Pastor, M Garcia-Tecedor… - Journal of the …, 2019 - ACS Publications
Oxygen vacancies are ubiquitous in metal oxides and critical to performance, yet the impact
of these states upon charge carrier dynamics important for photoelectrochemical and …

Synthesis of Large Surface‐Area g‐C3N4 Comodified with MnOx and Au‐TiO2 as Efficient Visible‐Light Photocatalysts for Fuel Production

F Raziq, L Sun, Y Wang, X Zhang… - Advanced Energy …, 2018 - Wiley Online Library
Herein, this study successfully fabricates porous g‐C3N4‐based nanocomposites by
decorating sheet‐like nanostructured MnOx and subsequently coupling Au‐modified …

Hematite photoanodes for water oxidation: electronic transitions, carrier dynamics, and surface energetics

J Li, H Chen, CA Triana, GR Patzke - Angewandte Chemie, 2021 - Wiley Online Library
We review the current understanding of charge carriers in model hematite photoanodes at
different stages. The origin of charge carriers is discussed based on the electronic structure …

In situ observation of picosecond polaron self-localisation in α-Fe2O3 photoelectrochemical cells

E Pastor, JS Park, L Steier, S Kim, M Grätzel… - Nature …, 2019 - nature.com
Abstract Hematite (α-Fe2O3) is the most studied artificial oxygen-evolving photo-anode and
yet its efficiency limitations and their origin remain unknown. A sub-picosecond …

Characterization of charge carrier behavior in photocatalysis using transient absorption spectroscopy

TJ Miao, J Tang - The Journal of Chemical Physics, 2020 - pubs.aip.org
Photocatalysis is a promising sustainable method to generate solar fuels for the future, as
well as having other applications such as water/air purification. However, the performance of …

Unveiling charge dynamics of visible light absorbing oxysulfide for efficient overall water splitting

V Nandal, R Shoji, H Matsuzaki, A Furube, L Lin… - Nature …, 2021 - nature.com
Abstract Oxysulfide semiconductor, Y2Ti2O5S2, has recently discovered its exciting
potential for visible-light-induced overall water splitting, and therefore, imperatively requires …

The band structure and optical absorption of hematite (α-Fe 2 O 3): a first-principles GW-BSE study

S Piccinin - Physical Chemistry Chemical Physics, 2019 - pubs.rsc.org
Hematite (α-Fe2O3) is a widely investigated photocatalyst material for the oxygen evolution
reaction, a key step in photoelectrochemical water splitting. Having a suitable band gap for …