Fe (II) redox chemistry in the environment

J Huang, A Jones, TD Waite, Y Chen, X Huang… - Chemical …, 2021 - ACS Publications
Iron (Fe) is the fourth most abundant element in the earth's crust and plays important roles in
both biological and chemical processes. The redox reactivity of various Fe (II) forms has …

Magnetite and green rust: synthesis, properties, and environmental applications of mixed-valent iron minerals

M Usman, JM Byrne, A Chaudhary, S Orsetti… - Chemical …, 2018 - ACS Publications
Mixed-valent iron [Fe (II)-Fe (III)] minerals such as magnetite and green rust have received a
significant amount of attention over recent decades, especially in the environmental …

A critical review on the mechanisms of persulfate activation by iron-based materials: Clarifying some ambiguity and controversies

K Hou, Z Pi, F Yao, B Wu, L He, X Li, D Wang… - Chemical Engineering …, 2021 - Elsevier
Iron-based materials, as a series of effective persulfate (PS) activators, have been utilized
extensively in PS-based advanced oxidation processes. However, there are some ambiguity …

Superoxide radical driving the activation of persulfate by magnetite nanoparticles: implications for the degradation of PCBs

GD Fang, DD Dionysiou, SR Al-Abed… - Applied Catalysis B …, 2013 - Elsevier
Magnetite nanoparticles (MNPs) are ubiquitous components of the subsurface environment,
and increasing attention has been paid to MNPs due to their highly reductive and …

Spectroscopic evidence for Fe (II)− Fe (III) electron transfer at the iron oxide− water interface

AGB Williams, MM Scherer - Environmental science & technology, 2004 - ACS Publications
Using the isotope specificity of 57Fe Mössbauer spectroscopy, we report spectroscopic
observations of Fe (II) reacted with oxide surfaces under conditions typical of natural …

Distribution and fate of military explosives and propellants in soil: a review

J Pichtel - Applied and Environmental Soil Science, 2012 - Wiley Online Library
Energetic materials comprise both explosives and propellants. When released to the
biosphere, energetics are xenobiotic contaminants which pose toxic hazards to ecosystems …

Construction of Fe3O4@ β-CD/g-C3N4 nanocomposite catalyst for degradation of PCBs in wastewater through photodegradation and heterogeneous Fenton …

H Wang, C Zhang, X Zhang, S Wang, Z **a… - Chemical Engineering …, 2022 - Elsevier
Herein, a multifunctional magnetic β-cyclodextrin/graphitic carbon nitride catalyst (Fe 3 O
4@ β-CD/gC 3 N 4) was fabricated for PCBs degradation in wastewater. The catalysts were …

Strategies for improving the electroactivity and specific metabolic functionality of microorganisms for various microbial electrochemical technologies

P Chiranjeevi, SA Patil - Biotechnology advances, 2020 - Elsevier
Electroactive microorganisms, which possess extracellular electron transfer (EET)
capabilities, are the basis of microbial electrochemical technologies (METs) such as …

Fe (II)-catalyzed recrystallization of goethite revisited

RM Handler, AJ Frierdich, CM Johnson… - … science & technology, 2014 - ACS Publications
Results from enriched 57Fe isotope tracer experiments have shown that atom exchange can
occur between structural Fe in Fe (III) oxides and aqueous Fe (II) with no formation of …

Reactivity of nanoscale zero-valent iron in unbuffered systems: effect of pH and Fe (II) dissolution

S Bae, K Hanna - Environmental science & technology, 2015 - ACS Publications
While most published studies used buffers to maintain the pH, there is limited knowledge
regarding the reactivity of nanoscale zerovalent iron (NZVI) in poorly buffered pH systems to …