Reactive high-valent iron intermediates in enhancing treatment of water by ferrate

VK Sharma, M Feng, DD Dionysiou… - Environmental …, 2021 - ACS Publications
Efforts are being made to tune the reactivity of the tetraoxy anion of iron in the+ 6 oxidation
state (FeVIO42–), commonly called ferrate, to further enhance its applications in various …

Degradation of organic chemicals in aqueous system through ferrate-based processes: A review

T He, B Zhou, H Chen, R Yuan - Journal of Environmental Chemical …, 2022 - Elsevier
Abstract Ferrate [Fe (VI)] has been proven to be an effective oxidant in wastewater treatment,
and Fe (VI)-based processes have been developed in refractory pollutants treatment. In this …

Enhanced oxidation of antibiotics by ferrate mediated with natural organic matter: role of phenolic moieties

B Guo, J Wang, K Sathiyan, X Ma… - Environmental …, 2023 - ACS Publications
The increasing presence of antibiotics in water sources threatens public health and
ecosystems. Various treatments have been previously applied to degrade antibiotics, yet …

Peracetic acid enhances micropollutant degradation by ferrate (VI) through promotion of electron transfer efficiency

J Wang, J Kim, DC Ashley, VK Sharma… - … Science & Technology, 2022 - ACS Publications
Ferrate (VI) and peracetic acid (PAA) are two oxidants of growing importance in water
treatment. Recently, our group found that simultaneous application of ferrate (VI) and PAA …

pH-Driven efficacy of the ferrate (VI)–peracetic acid system in swift sulfonamide antibiotic degradation: a deep dive into active species evolution and mechanistic …

XJ Chen, CW Bai, YJ Sun, XT Huang… - Environmental …, 2023 - ACS Publications
In the realm of wastewater treatment, the power of ferrate (Fe (VI)) and peracetic acid (PAA)
as oxidants stands out. But their combined might is where the enhancement truly lies. Their …

Efficient activation of ferrate (VI) by colloid manganese dioxide: Comprehensive elucidation of the surface-promoted mechanism

M Luo, H Zhang, P Zhou, Z **ong, B Huang, J Peng… - Water Research, 2022 - Elsevier
Current research focuses on introducing additional energy or reducing agents to directly
accelerate the formation of Fe (IV) and Fe (V) from ferrate (Fe (VI)), thereby ameliorating the …

Rapid and highly selective Fe (IV) generation by Fe (II)-peroxyacid advanced oxidation processes: Mechanistic investigation via kinetics and density functional theory

J Wang, J Kim, J Li, C Krall, VK Sharma… - Environmental …, 2024 - ACS Publications
High-valent iron (Fe (IV/V/VI)) has been widely applied in water decontamination. However,
common Fe (II)-activating oxidants including hydrogen peroxide (H2O2) and persulfate react …

Selective removal of emerging organic contaminants from water using electrogenerated Fe (IV) and Fe (V) under near-neutral conditions

S Wang, Y Lin, B Shao, H Dong, J Ma… - … Science & Technology, 2023 - ACS Publications
Fe (IV) and Fe (V) are promising oxidants for the selective removal of emerging organic
contaminants (EOCs) from water under near-neutral conditions. The Fe (III)-assisted …

Three kinetic patterns for the oxidation of emerging organic contaminants by Fe (VI): The critical roles of Fe (V) and Fe (IV)

S Wang, Y Deng, B Shao, J Zhu, Z Hu… - … Science & Technology, 2021 - ACS Publications
For the first time, this study showed that the apparent second-order rate constants (k app) of
six selected emerging organic contaminants (EOCs) oxidation by Fe (VI) increased …

Risks, characteristics, and control strategies of disinfection-residual-bacteria (DRB) from the perspective of microbial community structure

HB Wang, YH Wu, LW Luo, T Yu, A Xu, S Xue… - Water research, 2021 - Elsevier
The epidemic of COVID-19 has aroused people's particular attention to biosafety. A growing
number of disinfection products have been consumed during this period. However, the flaw …