Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W **g, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Understanding ligand-protected noble metal nanoclusters at work

MF Matus, H Häkkinen - Nature Reviews Materials, 2023 - nature.com
Ligand-protected noble metal nanoclusters, commonly termed 'monolayer-protected metal
clusters'(MPCs), comprise a common set of structures with an inorganic core stabilized by an …

Covalent organic frameworks (COFs) for electrochemical applications

X Zhao, P Pachfule, A Thomas - Chemical Society Reviews, 2021 - pubs.rsc.org
Covalent organic frameworks are a class of extended crystalline organic materials that
possess unique architectures with high surface areas and tuneable pore sizes. Since the …

Electrocatalysis for CO 2 conversion: from fundamentals to value-added products

G Wang, J Chen, Y Ding, P Cai, L Yi, Y Li… - Chemical Society …, 2021 - pubs.rsc.org
The continuously increasing CO2 released from human activities poses a great threat to
human survival by fluctuating global climate and disturbing carbon balance among the four …

Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R **, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Layered double hydroxide-derived nanomaterials for efficient electrocatalytic water splitting: Recent progress and future perspective

A Hameed, M Batool, Z Liu, MA Nadeem… - ACS Energy …, 2022 - ACS Publications
Layered double hydroxides (LDHs) have attracted intense interest in recent research and
hold promise in a vast range of applications. Because of the layered structure and diverse …

Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels

YY Birdja, E Pérez-Gallent, MC Figueiredo, AJ Göttle… - Nature Energy, 2019 - nature.com
The electrocatalytic reduction of carbon dioxide is a promising approach for storing (excess)
renewable electricity as chemical energy in fuels. Here, we review recent advances and …

Atomically Precise Copper Nanoclusters for Highly Efficient Electroreduction of CO2 towards Hydrocarbons via Breaking the Coordination Symmetry of Cu Site

QJ Wu, DH Si, PP Sun, YL Dong, S Zheng… - Angewandte …, 2023 - Wiley Online Library
We propose an effective highest occupied d‐orbital modulation strategy engendered by
breaking the coordination symmetry of sites in the atomically precise Cu nanocluster (NC) to …

Surface strategies for catalytic CO 2 reduction: from two-dimensional materials to nanoclusters to single atoms

L Wang, W Chen, D Zhang, Y Du, R Amal… - Chemical Society …, 2019 - pubs.rsc.org
Redox catalysis, including photocatalysis and (photo) electrocatalysis, may alleviate global
warming and energy crises by removing excess CO2 from the atmosphere and converting it …

Emerging two-dimensional nanomaterials for electrocatalysis

H **, C Guo, X Liu, J Liu, A Vasileff, Y Jiao… - Chemical …, 2018 - ACS Publications
Over the past few decades, the design and development of advanced electrocatalysts for
efficient energy conversion technologies have been subjects of extensive study. With the …