Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents

NS Bobbitt, ML Mendonca, AJ Howarth… - Chemical Society …, 2017‏ - pubs.rsc.org
Owing to the vast diversity of linkers, nodes, and topologies, metal–organic frameworks can
be tailored for specific tasks, such as chemical separations or catalysis. Accordingly, these …

<? ACS-CT-START-Insert?> Update 1 of:<? ACS-CT-END-Insert?> Destruction and Detection of Chemical Warfare Agents

… <? ACS-CT-START-Insert?> Jang<? ACS-CT … - Chemical …, 2015‏ - ACS Publications
Yang and co-workers appeared (Figure 1), 2 and 16 years since their accompanying
Accounts article,“Chemical Detoxification of Nerve Agent VX.” 14 Also, organophosphonate …

Mechanism and Kinetics for Reaction of the Chemical Warfare Agent Simulant, DMMP(g), with Zirconium(IV) MOFs: An Ultrahigh-Vacuum and DFT Study

G Wang, C Sharp, AM Plonka, Q Wang… - The Journal of …, 2017‏ - ACS Publications
The mechanism and kinetics of interactions between dimethyl methylphosphonate (DMMP),
a key chemical warfare agent (CWA) simulant, and Zr6-based metal organic frameworks …

Detoxification of Chemical Warfare Agents Using a Zr6‐Based Metal–Organic Framework/Polymer Mixture

SY Moon, E Proussaloglou… - … A European Journal, 2016‏ - Wiley Online Library
Owing to their high surface area, periodic distribution of metal sites, and water stability,
zirconium‐based metal–organic frameworks (Zr6‐MOFs) have shown promising activity for …

Reaction mechanism of nerve-agent decomposition with Zr-based metal organic frameworks

D Troya - The Journal of Physical Chemistry C, 2016‏ - ACS Publications
We present a detailed study of the decomposition of Sarin on the Zr-based UiO-66 and MOF-
808 metal organic frameworks (MOFs) using electronic structure calculations. The central …

Photoenhanced Degradation of Sarin at Cu/TiO2 Composite Aerogels: Roles of Bandgap Excitation and Surface Plasmon Excitation

PA DeSario, WO Gordon, A Balboa… - … Applied Materials & …, 2021‏ - ACS Publications
Multifunctional composites that couple high-capacity adsorbents with catalytic nanoparticles
(NPs) offer a promising route toward the degradation of organophosphorus pollutants or …

Force fields for molecular modeling of sarin and its simulants: DMMP and DIMP

A Emelianova, EA Basharova… - The Journal of …, 2021‏ - ACS Publications
Even three decades after signing the Chemical Weapons Convention, organophosphorus
chemical warfare agents (CWAs), such as sarin, remain a threat. The development of novel …

A molecular picture of surface interactions of organic compounds on prevalent indoor surfaces: limonene adsorption on SiO 2

Y Fang, PSJ Lakey, S Riahi, AT McDonald… - Chemical …, 2019‏ - pubs.rsc.org
Indoor surfaces are often coated with organic compounds yet a molecular understanding of
what drives these interactions is poorly understood. Herein, the adsorption and desorption of …

Chemical bridge-mediated heterojunction electron transport layers enable efficient and stable perovskite solar cells

P Patil, A Maibam, SS Sangale, DS Mann… - … Applied Materials & …, 2023‏ - ACS Publications
Perovskite solar cells (PSCs) emerged as potential photovoltaic energy-generating devices
develo** in recent years because of their excellent photovoltaic properties and ease of …

Microgravimetric thermodynamic modeling for optimization of chemical sensing nanomaterials

P Xu, H Yu, S Guo, X Li - Analytical Chemistry, 2014‏ - ACS Publications
On the basis of microgravimetric sensing data, an analytical modeling method is proposed
for comprehensive evaluation and optimization of gas sensing or adsorbing related …