The Staudinger reaction between phosphines and azides provides a straightforward route to
azaylides. Until the 1980s, it was thought that the putative intermediates of this reaction …

α-Glycosyl amides can be synthesized from the corresponding O-benzyl-α-glycosyl azides
using a traceless Staudinger ligation with diphenylphosphanyl-phenyl esters 4. All the …

The coupling of tertiary phosphines and azides, commonly referred to as the Staudinger
reaction (Scheme 1), provides a straightforward route to phosphazenes.[1] Numerous …

Staudinger reaction of α-azidophenylacetonitrile with triphenylphosphine in 1: 2 molar ratio
provides the triphenylphosphazine 4 derived from α-diazophenylacetonitrile, whereas in 2: 1 …

The lowest energy pathway for a Staudinger reaction between a phosphane and an azide is
predicted at the RHF and DFT ab initio SCF-MO level to proceed via an s-cis intermediate 7 …

The reactions of triphenylphosphine with the azido-ortho-closo-dicarbadodecaboranes 1-N3-
2-R-closo-1, 2-C2B10H10 [R= Me (1a), Ph (1b)] produce the stable and isolatable …

The Staudinger‐model reaction H3P (1)+ HN3 (2)→ H3P= NH (5)+ N2 (6) has been
investigated at the CCSD (T)/6‐31G**//MP2 (Full)/6‐31G* level. Primary products formed in …

FULL PAPER Page 1 Tripod ± Tripod Coupling of Triazides with Triphosphanes. The
Synthesis, Characterization, and Stability in Solution of New Cage Compounds: Chiral …

The self-assembly of tris (3-azidobenzyl) amines with 1, 1, 1-tris [(diphenylphosphino)
methyl] ethane via tripod–tripod coupling proceeds successfully to give chiral macrobicyclic …

Ungewöhnlich sind sowohl die Z‐Konfiguration der intracyclischen N N‐Bindung als auch
die Konformation der Triphos‐Gruppierung in 1. Dieser aus dem entsprechenden tripodalen …