Methane oxidation to methanol

NF Dummer, DJ Willock, Q He, MJ Howard… - Chemical …, 2022 - ACS Publications
The direct transformation of methane to methanol remains a significant challenge for
operation at a larger scale. Central to this challenge is the low reactivity of methane at …

Applications of zeolites to C1 chemistry: recent advances, challenges, and opportunities

Q Zhang, J Yu, A Corma - Advanced Materials, 2020 - Wiley Online Library
C1 chemistry, which is the catalytic transformation of C1 molecules including CO, CO2, CH4,
CH3OH, and HCOOH, plays an important role in providing energy and chemical supplies …

Small-pore zeolites: synthesis and catalysis

M Dusselier, ME Davis - Chemical reviews, 2018 - ACS Publications
In the past decade or so, small-pore zeolites have received greater attention than large-and
medium-pore molecular sieves that have historically dominated the literature. This is …

Intergrowth zeolites, synthesis, characterization, and catalysis

Y Wang, C Tong, Q Liu, R Han, C Liu - Chemical Reviews, 2023 - ACS Publications
Microporous zeolites that can act as heterogeneous catalysts have continued to attract a
great deal of academic and industrial interest, but current progress in their synthesis and …

Activation and conversion of alkanes in the confined space of zeolite-type materials

P Del Campo, C Martínez, A Corma - Chemical Society Reviews, 2021 - pubs.rsc.org
Microporous zeolite-type materials, with crystalline porous structures formed by well-defined
channels and cages of molecular dimensions, have been widely employed as …

Active sites and mechanisms in the direct conversion of methane to methanol using Cu in zeolitic hosts: a critical examination

MA Newton, AJ Knorpp, VL Sushkevich… - Chemical Society …, 2020 - pubs.rsc.org
In this critical review we examine the current state of our knowledge in respect of the nature
of the active sites in copper containing zeolites for the selective conversion of methane to …

Methane to methanol: structure–activity relationships for Cu-CHA

DK Pappas, E Borfecchia, M Dyballa… - Journal of the …, 2017 - ACS Publications
Cu-exchanged zeolites possess active sites that are able to cleave the C–H bond of
methane at temperatures≤ 200° C, enabling its selective partial oxidation to methanol …

Continuous partial oxidation of methane to methanol catalyzed by diffusion-paired copper dimers in copper-exchanged zeolites

KT Dinh, MM Sullivan, K Narsimhan… - Journal of the …, 2019 - ACS Publications
Copper-exchanged zeolites can continuously and selectively catalyze the partial oxidation
of methane to methanol using only oxygen and water at low temperatures, but the genesis …

Structure and Reactivity of Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-Ion-Exchanged Chabazite Catalyst for NH3-Mediated Selective Catalytic …

C Negri, T Selleri, E Borfecchia, A Martini… - Journal of the …, 2020 - ACS Publications
The NH3-mediated selective catalytic reduction (NH3-SCR) of NOx over Cu-ion-exchanged
chabazite (Cu-CHA) catalysts is the basis of the technology for abatement of NOx from …

Cu-CHA–a model system for applied selective redox catalysis

E Borfecchia, P Beato, S Svelle, U Olsbye… - Chemical Society …, 2018 - pubs.rsc.org
We review the structural chemistry and reactivity of copper-exchanged molecular sieves with
chabazite (CHA) topology, as an industrially applied catalyst in ammonia mediated …