Conspectus Catalytic atroposelective syntheses of axially chiral compounds have stimulated
extensive interest in multiple communities, such as synthetic chemistry, biochemistry, and …

Alkaloids are important chemical compounds that serve as a rich source for drug discovery.
Numerous alkaloids screened from medicinal plants and herbs showed antiproliferative and …

This study establishes the first organocatalytic enantioselective synthesis of axially chiral N,
N′‐bisindoles via chiral phosphoric acid‐catalyzed formal (3+ 2) cycloadditions of indole …

The first highly atroposelective construction of N− N axially chiral indole scaffolds was
established via a new strategy of de novo ring formation. This strategy makes use of the …

The construction of N–N axially chiral motifs is an important research topic, owing to their
wide occurrence in natural products, pharmaceuticals and chiral ligands. One efficient …

Enantioselective synthesis of N− N biaryl atropisomers is an emerging area but remains
underexplored. The development of efficient synthesis of N− N biaryl atropisomers is in great …

The catalytic asymmetric construction of N− N atropisomeric biaryls remains a formidable
challenge. Studies of them lag far behind studies of the more classical carbon‐carbon biaryl …

Axially chiral compounds have been always considered a laboratory curiosity with rare
prospects of being applied in asymmetric synthesis. Things have changed very quickly in the …

Nitrogen–nitrogen bonds containing motifs are ubiquitous in natural products and bioactive
compounds. However, the atropisomerism arising from a restricted rotation around an N–N …

The synthesis of N–N axially chiral molecules in the enantiopure form has emerged as an
interesting research topic primarily due to the significance and intricacy in synthesizing …