Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …

Borylations of inert carbon–hydrogen bonds are highly useful for transforming feedstock
chemicals into versatile organoboron reagents. Catalysis of these reactions has historically …

Ligands are the most commonly used means to control the regioselectivity of organic
reactions. It is very important to develop new regioselective control methods for organic …

Herein, we report a conceptually novel borylation reaction proceeding via a mild
photoinduced decarboxylation of redox-activated aromatic carboxylic acids. This work …

A rapid, chemoselective and metal-free C–B bond-forming reaction of aryl iodides and
bromides in aqueous solution at low temperatures was discovered. This reaction is …

We report herein an efficient and general method for the deboronofluorination of
alkylboronates. Thus, with the catalysis of AgNO3, the reactions of various alkylboronic acids …

A copper (II)-catalyzed borylation of alkyl halides with bis (pinacolato) diboron (B2pin2) has
been developed, which can be carried out in air, providing a wide range of primary …

Carboboration of alkynes was found to take place efficiently by a three-component coupling
reaction with diboron and carbon electrophiles under copper catalysis to afford diverse …

The first “in air” copper-catalyzed method for the selective synthesis of tri-and
tetrasubstituted vinylboronate derivatives is presented. Three different variants of the …