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Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges
IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …
Click chemistry strategies for the accelerated synthesis of functional macromolecules
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …
materials with precise control over architecture and functionality. In this review, we provide a …
Metal-catalyzed Markovnikov-type selective hydrofunctionalization of terminal alkynes
J Chen, WT Wei, Z Li, Z Lu - Chemical Society Reviews, 2024 - pubs.rsc.org
Metal-catalyzed highly Markovnikov-type selective hydrofunctionalization of terminal alkynes
provides a straightforward and atom-economical route to access 1, 1-disubstituted alkenes …
provides a straightforward and atom-economical route to access 1, 1-disubstituted alkenes …
Stereochemical enhancement of polymer properties
The importance of stereochemistry to the function of molecules is generally well understood.
However, to date, control over stereochemistry and its potential to influence properties of the …
However, to date, control over stereochemistry and its potential to influence properties of the …
Metal-catalyzed regiodivergent organic reactions
C Nájera, IP Beletskaya, M Yus - Chemical Society Reviews, 2019 - pubs.rsc.org
Metal-catalyzed regiodivergent reactions allow control over regioselectivity in the synthesis
of a wide range of organic products. Starting from the same material, it is possible to prepare …
of a wide range of organic products. Starting from the same material, it is possible to prepare …
X‐yne click polymerization
X Fu, A Qin, BZ Tang - Aggregate, 2023 - Wiley Online Library
Alkyne‐based click polymerizations have been nurtured into a powerful synthetic technique
for the preparation of new polymers with advanced structures and versatile properties …
for the preparation of new polymers with advanced structures and versatile properties …
Recent advances in catalytic sequential reactions involving hydroelement addition to carbon–carbon multiple bonds
X Zeng - Chemical reviews, 2013 - ACS Publications
Sequential reactions, through the incorporation of several distinct transformations into one
single sequence, are one of the most powerful synthetic tools in modern organic chemistry …
single sequence, are one of the most powerful synthetic tools in modern organic chemistry …
Organocatalytic carbon–sulfur bond-forming reactions
P Chauhan, S Mahajan, D Enders - Chemical reviews, 2014 - ACS Publications
Carbon− heteroatom bond formations are very important reactions in organic synthesis and
have attracted the interest of many synthetic organic chemists, leading them to develop new …
have attracted the interest of many synthetic organic chemists, leading them to develop new …
Metal-free organocatalytic S-formylation of thiols using CO2
S-formylation of thiols is achieved via an enzymatic process catalysed by formate
dehydrogenase enzyme that fixes CO2 onto substrates, which plays a crucial role in …
dehydrogenase enzyme that fixes CO2 onto substrates, which plays a crucial role in …
Catalytic hydrothiolation: regio-and enantioselective coupling of thiols and dienes
We report a Rh-catalyzed hydrothiolation of 1, 3-dienes, including petroleum feedstocks.
Either secondary or tertiary allylic sulfides can be generated from the selective addition of a …
Either secondary or tertiary allylic sulfides can be generated from the selective addition of a …