The difunctionalization of carbon–carbon double bonds, introducing two novel functional
groups onto both sides of the carbon–carbon bond in one pot, has become more and more …

This review discusses recent advances in the chemistry of saturated boronic acids,
boronates, and trifluoroborates. Applications of the title compounds in the design of boron …

Enantioselective difunctionalization of alkenes constitutes an efficient strategy to assemble
complex chiral molecules from simple racemic or achiral starting materials. Here we present …

While chain‐walking stimulates wide interest in both polymerization and organic synthesis,
site‐and stereoselective control of chain‐walking on rings is still a challenging task in the …

The four-electron (4e−) oxygen reduction reaction (ORR) is a basic reaction in fuel cells and
metal–air batteries, but its wide use requires the development of efficient and inexpensive …

Stereochemically pure saccharides have indispensable roles in fields ranging from
medicinal chemistry to materials science and organic synthesis. However, the development …

Explorations of multifunctional catalysts for electrochemical reactions, such as oxygen
electrocatalysis and CO 2 electroreduction, are key issues for energy crisis and global …

Whereas there is a significant interest in the rapid construction of diversely substituted
saturated heterocycles, direct and modular access is currently limited to the mono-, 2, 3-, or …

Secondary α, α‐dialkyl boronates are widely used due to their great versatility. Herein we
report an unprecedented deoxygenative alkylboration of aldehydes, a facile method to …

Abstract A catalytic 1, 1‐difunctionalization of unactivated olefins en route to sp3 bis‐
organometallic B, B (Si)‐reagents is described. The protocol is characterized by exceptional …