Ligands on Nanocrystal Surfaces, the 1H Nuclear Magnetic Resonance Fingerprint
Z Hens - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Surfaces are an integral part of colloidal nanocrystals (NCs). Hence,
understanding the binding and packing to NC surfaces of organic ligands, which are often …
understanding the binding and packing to NC surfaces of organic ligands, which are often …
Thermodynamics of nanocrystal–ligand binding through isothermal titration calorimetry
AB Greytak, SL Abiodun, JM Burrell, EN Cook… - Chemical …, 2022 - pubs.rsc.org
Manipulations of nanocrystal (NC) surfaces have propelled the applications of colloidal NCs
across various fields such as bioimaging, catalysis, electronics, and sensing applications. In …
across various fields such as bioimaging, catalysis, electronics, and sensing applications. In …
Evidence and structural insights into a ligand-mediated phase transition in the solvated ligand shell of quantum dots
As synthesized, nanocrystal surfaces are typically covered in coordinating organic ligands,
and the degree of packing and order of these ligands are ongoing questions in the field of …
and the degree of packing and order of these ligands are ongoing questions in the field of …
Extremely long-lived charge donor states formed by visible irradiation of quantum dots
MK Homer, HC Larson, GJ Dixon, E Miura-Stempel… - ACS …, 2024 - ACS Publications
Using cyclic voltammetry under illumination, we recently demonstrated that CdS quantum
dots (QDs) form charge donor states that live for at least several minutes after illumination …
dots (QDs) form charge donor states that live for at least several minutes after illumination …
Reductive pathways in molten inorganic salts enable colloidal synthesis of III-V semiconductor nanocrystals
Colloidal quantum dots, with their size-tunable optoelectronic properties and scalable
synthesis, enable applications in which inexpensive high-performance semiconductors are …
synthesis, enable applications in which inexpensive high-performance semiconductors are …
Metal-Dictated Reactivity of Z-Type Ligands to Passivate Surface Defects on CdSe Nanocrystals
JE Kelm, JL Dempsey - Journal of the American Chemical Society, 2024 - ACS Publications
Accessing semiconductor nanocrystals free from surface defects is an outstanding challenge
in the design of materials with targeted properties. Despite the established importance of Z …
in the design of materials with targeted properties. Despite the established importance of Z …
Ligand-Induced Size-Dependent Circular Dichroism in Quantum Dots
Recent experiments have probed the chiral properties of semiconductor nanocrystal (NC)
quantum dots (QDs), but understanding the circular dichroism line shape, excitonic features …
quantum dots (QDs), but understanding the circular dichroism line shape, excitonic features …
Measuring Relative Energies of Ligand Binding Conformations on Nanocluster Surfaces with Temperature-Dependent FTIR Spectroscopy
MD Klein, CH Bisted, FY Dou… - The Journal of …, 2023 - ACS Publications
We present a method to measure relative energies between binding conformations of
carboxylate ligands on InP magic-sized clusters in solution. Using Markov chain Monte …
carboxylate ligands on InP magic-sized clusters in solution. Using Markov chain Monte …
Ligand Exchange of Quantum Dots: A Thermodynamic Perspective
M Liu, G Tang, Y Liu, FL Jiang - The Journal of Physical Chemistry …, 2024 - ACS Publications
Colloidal quantum dots (QDs) consist of an inorganic core and organic surface ligands.
Surface ligands play a dominant role in maintaining the colloidal stability of QDs and …
Surface ligands play a dominant role in maintaining the colloidal stability of QDs and …
Spontaneous patterning of binary ligand mixtures on CdSe nanocrystals: From random to Janus packing
Binary compositions of surface ligands are known to improve the colloidal stability and
fluorescence quantum yield of nanocrystals (NCs), due to ligand–ligand interactions and …
fluorescence quantum yield of nanocrystals (NCs), due to ligand–ligand interactions and …