Melting Is Well-Known, but Is It Also Well-Understood?

G de With - Chemical Reviews, 2023 - ACS Publications
Contrary to continuous phase transitions, where renormalization group theory provides a
general framework, for discontinuous phase transitions such a framework seems to be …

Thermodynamics at the nanoscale: A new approach to the investigation of unique physicochemical properties of nanomaterials

CC Yang, YW Mai - Materials Science and Engineering: R: Reports, 2014 - Elsevier
An extension of the classic thermodynamics theory to nanometer scale has generated a new
interdisciplinary theory–nanothermodynamics. It serves as a bridge between macroscopic …

Modeling of the melting point, Debye temperature, thermal expansion coefficient, and the specific heat of nanostructured materials

YF Zhu, JS Lian, Q Jiang - The Journal of Physical Chemistry C, 2009 - ACS Publications
The size-dependences of the melting point, Debye temperature, thermal expansion
coefficient, and the specific heat of nanostructured materials have been modeled free of …

Energy electronegativity and chemical bonding

SS Batsanov - Molecules, 2022 - mdpi.com
Historical development of the concept of electronegativity (EN) and its significance and
prospects for physical and structural chemistry are discussed. The current cutting-edge …

Size-dependent melting point of nanoparticles based on bond number calculation

H Li, PD Han, XB Zhang, M Li - Materials Chemistry and Physics, 2013 - Elsevier
An integrated model based on bond number and bond strength in a system with a cubo-
octahedral structure is developed to predict the size-dependent thermal characteristics of …

Effective coordination number model for the size dependency of physical properties of nanocrystals

MA Shandiz - Journal of Physics: Condensed Matter, 2008 - iopscience.iop.org
Based on the effective coordination number (ECN) viewpoint a model for the size
dependency of cohesive energy of nanocrystals has been developed. In order to calculate …

Temperature and size dependent surface energy of metallic nano-materials

X Zhang, W Li, H Kou, J Shao, Y Deng… - Journal of Applied …, 2019 - pubs.aip.org
In this study, we report a theoretical model for the temperature and size dependent surface
energy of metallic nanomaterials. The model is verified by making a comparison with the …

Transparent Colloids of Detonation Nanodiamond: Physical, Chemical and Biological Properties

SS Batsanov, SM Gavrilkin, DA Dan'kin, AS Batsanov… - Materials, 2023 - mdpi.com
Aqueous suspensions (colloids) containing detonation nano-diamond (DND) feature in most
applications of DND and are an indispensable stage of its production; therefore, the …

Size-dependent thermal stability and the smallest nanocrystal

A Safaei, MA Shandiz - Physica E: Low-dimensional Systems and …, 2009 - Elsevier
The lattice-type-sensitive model for the melting entropy and enthalpy of nanocrystals has
been presented based on a model for the size dependency of the melting point. In other …

In situ heating characterization of structural evolution and size-dependent melting point depression in gold nanoclusters: a comprehensive thermodynamic …

S Hu, KJ Hu, Z Zhao, Y Zhang, SA Shah, S Lu, W Zhu… - Nanoscale, 2024 - pubs.rsc.org
The investigation of nanocluster behaviors at elevated temperatures is important because it
encompasses temperature-dependent structural evolution and size-dependent melting …