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Progress in the self-assembly of organic/inorganic polyhedral oligomeric silsesquioxane (POSS) hybrids
This Review describes recent progress in the self-assembly of organic/inorganic POSS
hybrids derived from mono-, di-, and multi-functionalized POSS cages. We highlight the self …
hybrids derived from mono-, di-, and multi-functionalized POSS cages. We highlight the self …
Scaling perspective on dynamics of nanoparticles in polymers: length-and time-scale dependent nanoparticle–polymer coupling
T Ge - Macromolecules, 2023 - ACS Publications
The motion of nanoparticles in a polymer matrix is dictated by the intricate coupling of the
nanoparticles and surrounding polymers. Various length-and time-scale dependent features …
nanoparticles and surrounding polymers. Various length-and time-scale dependent features …
[HTML][HTML] Filled Elastomers: Mechanistic and Physics-Driven Modeling and Applications as Smart Materials
Elastomers are made of chain-like molecules to form networks that can sustain large
deformation. Rubbers are thermosetting elastomers that are obtained from irreversible …
deformation. Rubbers are thermosetting elastomers that are obtained from irreversible …
Dynamic covalent bond exchange enhances penetrant diffusion in dense vitrimers
Polymer membranes are commonly pursued for passive separations, which require less
energy than distillation. Typically, glassy materials are chosen for gas separations due to …
energy than distillation. Typically, glassy materials are chosen for gas separations due to …
Role of polymer–nanoparticle interactions on the fracture toughness of polymer-infiltrated nanoparticle films
Polymer–nanoparticle (NP) composite films (PNCFs) with extremely high loadings of NPs (>
50 vol%) have superb transport, thermal, and electrical properties. A new class of highly …
50 vol%) have superb transport, thermal, and electrical properties. A new class of highly …
Mechanical reinforcement by bridging chains in polymer nanocomposites
W Cui, J Liu, W You, W Yu - Polymer, 2024 - Elsevier
The adsorption-induced bridging of polymer chains between adjacent nanoparticles was
studied in poly (vinyl acetate)/silica nanocomposites with different polymer molecular …
studied in poly (vinyl acetate)/silica nanocomposites with different polymer molecular …
Bioinspired pullulan-starch nanoplatelets nanocomposite films with enhanced mechanical properties
Q **ao, M Dai, M Huang, LT Lim - Carbohydrate Polymers, 2024 - Elsevier
Inspired by the leaf-vein network structure, the pullulan-starch nanoplatelets (SNPs)
bioinspired films with enhanced strength and toughness were successfully fabricated …
bioinspired films with enhanced strength and toughness were successfully fabricated …
Structural and dynamical roles of bound polymer chains in rubber reinforcement
The addition of nanofillers to rubber matrices is a powerful route to improve the mechanical
properties. Here, we focus on a molecular understanding of basic mechanisms that are …
properties. Here, we focus on a molecular understanding of basic mechanisms that are …
Nanoparticle Diffusion in Miscible Polymer Nanocomposite Melts
X-ray photon correlation spectroscopy measurements were used to quantify the dynamics of
bare and bimodal grafted silica nanoparticles mixed with PEO melts of different molecular …
bare and bimodal grafted silica nanoparticles mixed with PEO melts of different molecular …
Reversible reactions, mesh size, and segmental dynamics control penetrant diffusion in ethylene vitrimers
The diffusion of two aromatic dyes with nearly identical sizes was measured in ethylene
vitrimers with precise linker lengths and borate ester cross-links using fluorescence recovery …
vitrimers with precise linker lengths and borate ester cross-links using fluorescence recovery …