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Advancements in Novel Mechano-Rheological Probes for Studying Glassy Dynamics in Nanoconfined Thin Polymer Films
The nanoconfinement effects of glassy polymer thin films on their thermal and mechanical
properties have been investigated thoroughly, especially with an emphasis on its altered …
properties have been investigated thoroughly, especially with an emphasis on its altered …
A direct quantitative measure of surface mobility in a glassy polymer
Thin polymer films have striking dynamical properties that differ from their bulk counterparts.
With the simple geometry of a stepped polymer film on a substrate, we probe mobility above …
With the simple geometry of a stepped polymer film on a substrate, we probe mobility above …
Thermocapillary approaches to the deliberate patterning of polymers
JP Singer - Journal of Polymer Science Part B: Polymer …, 2017 - Wiley Online Library
The phenomenon of thermocapillarity, the response of fluids to thermal gradients due to
thermal alteration of their surface tension, was first reported over a century ago. Since then …
thermal alteration of their surface tension, was first reported over a century ago. Since then …
Polymer Thin Film Necking: Ductility from Entanglements and Plane Stress Condition
The ductility of polymer thin films is critical to many applications such as organic electronics
and separation membranes. Large-scale molecular simulations are performed to reproduce …
and separation membranes. Large-scale molecular simulations are performed to reproduce …
Invariant fast diffusion on the surfaces of ultrastable and aged molecular glasses
Surface diffusion of molecular glasses is found to be orders of magnitude faster than bulk
diffusion, with a stronger dependence on the molecular size and intermolecular interactions …
diffusion, with a stronger dependence on the molecular size and intermolecular interactions …
Deformation and relaxation of viscous thin films under bouncing drops
Thin, viscous liquid films subjected to impact events can deform. Here we investigate free-
surface oil-film deformations that arise owing to the build up of air under the impacting and …
surface oil-film deformations that arise owing to the build up of air under the impacting and …
Beyond Tanner's Law: Crossover between Spreading Regimes of a Viscous Droplet<? format?> on an Identical Film
We present results on the leveling of polymer microdroplets on thin films prepared from the
same material. In particular, we explore the crossover from a droplet spreading on an …
same material. In particular, we explore the crossover from a droplet spreading on an …
Using tobacco mosaic virus to probe enhanced surface diffusion of molecular glasses
Recent studies have shown that diffusion on the surface of organic glasses can be many
orders of magnitude faster than bulk diffusion. Develo** new probes that can readily …
orders of magnitude faster than bulk diffusion. Develo** new probes that can readily …
Capillary levelling of a cylindrical hole in a viscous film
The capillary levelling of cylindrical holes in viscous polystyrene films was studied using
atomic force microscopy as well as quantitative analytical scaling arguments based on thin …
atomic force microscopy as well as quantitative analytical scaling arguments based on thin …
Numerical solutions of thin-film equations for polymer flows
We report on the numerical implementation of thin-film equations that describe the capillary-
driven evolution of viscous films, in two-dimensional configurations. After recalling the …
driven evolution of viscous films, in two-dimensional configurations. After recalling the …