A Review: Synthesis of Aryl C-Glycosides Via the Heck Coupling Reaction

KW Wellington, SA Benner - Nucleosides, Nucleotides, and Nucleic …, 2006 - Taylor & Francis
In this article, we focus on the synthesis of aryl C-glycosides via Heck coupling. It is
organized based on the type of structures used in the assembly of the C-glycosides (also …

C-Glycopyranosyl aldehydes: emerging chiral synthons in organic synthesis

S Kumar, V Khatri, P Mangla, RJ Chhatwal… - RSC …, 2023 - pubs.rsc.org
Herein, we have summarized the vast array of synthetic processes that have been
developed for the synthesis of C-glycopyranosyl aldehydes and diverse C-glycoconjugates …

The use of levoglucosenone and isolevoglucosenone as templates for the construction of C-linked disaccharides

L Awad, R Demange, YH Zhu, P Vogel - Carbohydrate research, 2006 - Elsevier
Because of their functionalities (enone, ketone, and acetal) and their bicyclic structure (steric
factors), levoglucosenone (1, 6-anhydro-3, 4-dideoxy-β-d-glycero-hex-3-enopyran-2-ulose) …

Synthesis of chemical tools to improve water solubility and promote the delivery of salinomycin to cancer cells

L Awad - Experimental and Therapeutic Medicine, 2020 - spandidos-publications.com
Chemotherapy and radiation are unable to eliminate all cancer cells, particularly apoptosis‑
resistant cancer cells, despite their ability to kill cancer cluster cells. Thus, it is important to …

Stereoselective preparation of four 3-C-mannosylated d-and l-glucals from a single starting compound

Z Lövyova, K Parkan, L Kniežo - Tetrahedron, 2011 - Elsevier
The corresponding oxadiene, prepared from the starting perbenzylated α-d-
mannopyranosylethanal was subjected to stereoselective cycloaddition reactions with R and …

C‐Linked Disaccharide Analogue of the Thomsen–Friedenreich (T)‐Epitope α‐O‐Conjugated to L‐Serine

L Awad, J Riedner, P Vogel - Chemistry–A European Journal, 2005 - Wiley Online Library
Condensation of a silylated β‐d‐galactopyranosylaldehyde (3) with isolevoglucosenone (4)
in the presence of Et2AlI provided bicyclic enone 5. Subsequent addition of BnNHOMe gave …

Synthesis of C-Disaccharides through a One-Pot Alkynol Cycloisomerization-Reductive Deoxygenation.

SB Narute, JK Rout… - Chemistry-A European …, 2013 - search.ebscohost.com
A sweet disposition: Simple protocols for the synthesis of (1→ 1)‐and (1→ 6)‐linked C‐
disaccharides have been developed (see scheme). A one‐pot Au‐catalyzed alkynol …

Silyl methallylsulfinates: efficient and powerful agents for the chemoselective silylation of alcohols, polyols, phenols and carboxylic acids

X Huang, C Craita, L Awad, P Vogel - Chemical communications, 2005 - pubs.rsc.org
Silyl methallylsulfinates: efficient and powerful agents for the chemoselective silylation of
alcohols, polyols, phenols and carboxylic acids - Chemical Communications (RSC Publishing) …

An approach to stereoselective preparation of 3-C-glycosylated D-and L-glucals

K Parkan, L Werner, Z Lövyová, E Prchalová… - Carbohydrate …, 2010 - Elsevier
An approach to stereoselective synthesis of α-or β-3-C-glycosylated l-or d-1, 2-glucals
starting from the corresponding α-or β-glycopyranosylethanals is described. The key step of …

Synthesis of C-disaccharides via a hetero-Diels–Alder reaction and further stereocontrolled transformations

Q Wan, A Lubineau, R Guillot, MC Scherrmann - Carbohydrate research, 2008 - Elsevier
The partial de novo synthesis of two new C-disaccharides containing d-glucosamine is
described. The strategy is based on a hetero-Diels–Alder reaction leading to a 1: 1 mixture …