Oxygen vacancy chemistry in oxide cathodes

YH Zhang, S Zhang, N Hu, Y Liu, J Ma, P Han… - Chemical Society …, 2024 - pubs.rsc.org
Secondary batteries are a core technology for clean energy storage and conversion
systems, to reduce environmental pollution and alleviate the energy crisis. Oxide cathodes …

Facilitating Layered Oxide Cathodes Based on Orbital Hybridization for Sodium‐Ion Batteries: Marvelous Air Stability, Controllable High Voltage, and Anion Redox …

XB Jia, J Wang, YF Liu, YF Zhu, JY Li, YJ Li… - Advanced …, 2024 - Wiley Online Library
Layered oxides have become the research focus of cathode materials for sodium‐ion
batteries (SIBs) due to the low cost, simple synthesis process, and high specific capacity …

Unveiling the Evolution of LiCoO2 beyond 4.6 V

Z Wu, G Zeng, J Yin, CL Chiang, Q Zhang… - ACS Energy …, 2023 - ACS Publications
The working mechanism of LiCoO2 beyond 4.6 V presents complicated issues:(1) the
ambiguous multistructural evolutions,(2) the vague O-related anionic redox reactions (ARR) …

Correlating concerted cations with oxygen redox in rechargeable batteries

S Wang, L Wang, S David, T Liu, C Zhan… - Chemical Society …, 2024 - pubs.rsc.org
Rechargeable batteries currently power much of our world, but with the increased demand
for electric vehicles (EVs) capable of traveling hundreds of miles on a single charge, new …

Molecular‐Level Design of High Flash Point Solvents Enables High‐Safety and Dual‐Function Chemical Presodiation of Hard Carbon and Alloy Anodes for High …

Q Man, C Wei, K Tian, H Shen, X Zhang… - Advanced Energy …, 2024 - Wiley Online Library
Hard carbon (HC) is subjected to low initial Coulombic efficiency (ICE) and unsteady solid
electrolyte interphase (SEI), which limits the energy density and cycling performance …

Resonant inelastic X-ray scattering

FMF de Groot, MW Haverkort, H Elnaggar… - Nature Reviews …, 2024 - nature.com
Resonant inelastic X-ray scattering (RIXS) is a powerful technique that combines
spectroscopy and inelastic scattering to probe the electronic structure of materials. RIXS is …

A universal interfacial reconstruction strategy based on converting residual alkali for sodium layered oxide cathodes: marvelous air stability, reversible anion redox …

LY Kong, JY Li, HX Liu, YF Zhu, J Wang… - Journal of the …, 2024 - ACS Publications
Mn-based layered oxide cathodes have attracted widespread attention due to high capacity
and low cost, however, poor air stability, irreversible phase transitions, and slow kinetics …

Challenges and strategies toward practical application of layered transition metal oxide cathodes for sodium-ion batteries

Y Liu, YH Zhang, J Ma, J Zhao, X Li… - Chemistry of Materials, 2023 - ACS Publications
Sodium-ion batteries (SIBs) are leading candidates to address the energy crisis and lithium
depletion. Layered transition metal (TM) oxides are regarded as some of the most promising …

Highly reversible transition metal migration in superstructure-free Li-rich oxide boosting voltage stability and redox symmetry

T Cui, J Xu, X Wang, L Liu, Y **ang, H Zhu, X Li… - Nature …, 2024 - nature.com
The further practical applications of Li-rich layered oxides are impeded by voltage decay
and redox asymmetry, which are closely related to the structural degradation involving …

Insights into Cation Migration and Intermixing in Advanced Cathode Materials for Lithium‐Ion Batteries

S Zhang, Z Yang, Y Lu, W **e, Z Yan… - Advanced Energy …, 2024 - Wiley Online Library
Cathode materials are the core components of lithium‐ion batteries owing to the
determination of the practical voltage and effective energy of the battery system. However …