One atom can make all the difference: gas-induced phase transformations in bisimidazole-linked diamondoid coordination networks

K Koupepidou, VI Nikolayenko… - Journal of the …, 2023 - ACS Publications
Coordination networks (CNs) that undergo gas-induced transformation from closed
(nonporous) to open (porous) structures are of potential utility in gas storage applications …

Water vapour and gas induced phase transformations in an 8-fold interpenetrated diamondoid metal–organic framework

A Subanbekova, VI Nikolayenko… - Journal of Materials …, 2023 - pubs.rsc.org
In this work, we report the synthesis, structural characterisation and sorption properties of an
8-fold interpenetrated diamondoid (dia) metal–organic framework (MOF) that is sustained by …

Insight into the Gas-Induced Phase Transformations in a 2D Switching Coordination Network via Coincident Gas Sorption and In Situ PXRD

SQ Wang, V Bon, S Darwish, SM Wang… - ACS Materials …, 2024 - ACS Publications
Switching coordination networks (CNs) that reversibly transform between narrow or closed
pore (cp) and large pore (lp) phases, though fewer than their rigid counterparts, offer …

Adsorbate-dependent phase switching in the square lattice topology coordination network [Ni (4, 4′-bipyridine) 2 (NCS) 2] n

SQ Wang, S Darwish, MJ Zaworotko - Chemical Communications, 2023 - pubs.rsc.org
Switching coordination networks (CNs) featuring stepped sorption isotherms that are
accompanied by phase changes offer promise for gas storage and separation applications …

The impact of solution vs. slurry vs. mechanochemical syntheses upon the sorption performance of a 2D switching coordination network

SQ Wang, S Darwish, MJ Zaworotko - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
The selection and optimization of synthesis routes for porous metal–organic materials are
critical for their large-scale manufacture but remain largely underexplored. In this study, we …

Pressure-induced structural effects in the square lattice (sql) topology coordination network Sql-1-Co-NCS· 4OX

E Patyk-Kazmierczak, M Kaźmierczak… - Crystal Growth & …, 2022 - ACS Publications
A high-pressure study of a switching coordination network of square lattice topology (sql)
loaded with o-xylene (OX),[Co (4, 4′-bipyridine) 2 (NCS) 2] n· 4nC8H10 (sql-1-Co-NCS …

Water sorption performance of the zeolitic metal azolate framework MAF-7

SQ Wang, S Darwish, MY Gao, Y Luo, J Zhu… - Chemical …, 2025 - pubs.rsc.org
Water sorption isotherms of [Zn (mtz) 2] n (MAF-7) were collected over a wide temperature
range (15–45° C) and its water sorption performance was assessed in terms of water …

Phase switching and shape-memory effect in a molecular material: revisiting the Werner complex [Ni (4-MePy) 4 (NCS) 2]

SQ Wang, S Darwish, CRMO Matos… - Inorganic Chemistry …, 2024 - pubs.rsc.org
Shape-memory effects and stimuli-induced phase transformations are observed across
many types of materials but remain understudied in molecular materials. In this contribution …

Ionic Liquid-Functionalization Metal-Organic Framework for Efficient C2h2/Co2 Separation

X Gu, M Liu, X Wang, L Zhang, S Wang, J Ma… - Available at SSRN … - papers.ssrn.com
Efficiently sieving C2H2 from CO2 remains a daunting challenge due to their similar
molecular sizes and physical properties. To address this issue, we have developed a novel …