The transition metal-catalysed hydroboration reaction
The use of transition metals to catalyse the addition of hydridoboranes to unsaturated
organic molecules was initially realised several decades ago. Although this area of …
organic molecules was initially realised several decades ago. Although this area of …
Recent advances in the synthesis and reactivity of MIDA boronates
Organoboron compounds have a wide-range of applications in synthetic methodologies,
natural products, and bioactive molecule synthesis. The sensitivity of boronic acid toward …
natural products, and bioactive molecule synthesis. The sensitivity of boronic acid toward …
Catalytic asymmetric synthesis of chiral propargylic boron compounds through B–H bond insertion reactions
Chiral propargylic boron compounds have a diverse array of potential applications. Although
numbers of highly enantioselective methodologies for the synthesis of other organoboron …
numbers of highly enantioselective methodologies for the synthesis of other organoboron …
Recent developments in the asymmetric synthesis and functionalization of symmetrical and unsymmetrical gem-diborylalkanes
gem-Diborylalkanes are an important class of organoboron compounds as they function as
a key building block in organic synthesis. In the last decade, there has been growing interest …
a key building block in organic synthesis. In the last decade, there has been growing interest …
Axially chiral α-boryl-homoallenyl boronic esters as versatile toolbox for accessing centrally and axially chiral molecules
Y **, J Lee, W Jo, J Yu, SH Cho - Nature Communications, 2024 - nature.com
Axially chiral allenes bearing organoboron groups are highly sought-after building blocks in
organic synthesis due to their potential for generating a wide range of axially and centrally …
organic synthesis due to their potential for generating a wide range of axially and centrally …
Pt(PPh3)4 and Pt(PPh3)4@IL catalyzed hydroboration of ketones
An efficient method for the reduction of various ketones via [Pt (PPh3) 4]-catalyzed
hydroboration with HBpin has been successfully developed for the first time. The protocol is …
hydroboration with HBpin has been successfully developed for the first time. The protocol is …
Synthesis and reactivity of alkynyl boron compounds
Over the last century, there have been considerable developments in organoboron
chemistry due to the stability, non-toxicity, and easy commercial availability of various …
chemistry due to the stability, non-toxicity, and easy commercial availability of various …
Copper-Catalyzed Reactions of Alkenyl Boronic Esters via Chan–Evans–Lam Coupling/Annulation Cascades: Substrate Selective Synthesis of Dihydroquinazolin-4 …
Y Li, Z Cao, Z Wang, L Xu, Y Wei - Organic Letters, 2022 - ACS Publications
Copper-catalyzed cascade cyclization reactions between alkenyl boronic esters and N–H-
based nucleophiles have been established, providing new approaches for one-pot …
based nucleophiles have been established, providing new approaches for one-pot …
Iron‐Catalyzed Borylation of Propargylic Acetates for the Synthesis of Multisubstituted Allenylboronates
A novel iron‐catalyzed borylation of propargylic acetates leading to allenylboronates has
been developed. The method allows the preparation of a variety of di‐, tri‐and …
been developed. The method allows the preparation of a variety of di‐, tri‐and …
Copper‐Catalyzed Preparation of Alkenylboronates and Arylboronates
S Alam, R Karim, A Khan, AK Pal… - European Journal of …, 2021 - Wiley Online Library
Organoboron compounds, especially alkenylboronates and arylboronates are highly useful
reagents and versatile building blocks in the modern synthetic chemistry toolbox. This …
reagents and versatile building blocks in the modern synthetic chemistry toolbox. This …