Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Homogeneously catalyzed electroreduction of carbon dioxide—methods, mechanisms, and catalysts

R Francke, B Schille, M Roemelt - Chemical reviews, 2018 - ACS Publications
The utilization of CO2 via electrochemical reduction constitutes a promising approach
toward production of value-added chemicals or fuels using intermittent renewable energy …

Molecular catalysts for CO2 Electroreduction: Progress and prospects with pincer type complexes

HA Younus, N Ahmad, W Ni, X Wang, M Al-Abri… - Coordination Chemistry …, 2023 - Elsevier
Transforming wastes or hazardous materials into value-added chemical products is of great
concern from economic, environmental, and sustainable prospects. Various approaches …

Determining the overpotential of electrochemical fuel synthesis mediated by molecular catalysts: Recommended practices, standard reduction potentials, and …

BM Stratakes, JL Dempsey, AJM Miller - ChemElectroChem, 2021 - Wiley Online Library
Molecular catalysts capable of performing electrochemical transformations are frequently
utilized in the synthesis of fuels. A common benchmark for evaluating catalysts for …

Metal‐Terpyridine Complexes in Catalytic Application–A Spotlight on the Last Decade

A Winter, US Schubert - ChemCatChem, 2020 - Wiley Online Library
Abstract 2, 2′: 6′, 2′′‐Terpyridine (tpy) and its derivatives represent highly versatile
ligands for the complexation of transition metal ions. Today, such complexes are employed …

New Ru (II) photocages operative with near-IR light: new platform for drug delivery in the PDT window

MH Al-Afyouni, TN Rohrabaugh, KF Al-Afyouni… - Chemical …, 2018 - pubs.rsc.org
A series of Ru (II) complexes bearing the tridentate 2, 6-di (quinolin-2-yl) pyridine (dqpy)
ligand were designed to undergo photoinduced ligand dissociation with red/near-IR light …

A look at periodic trends in d-block molecular electrocatalysts for CO 2 reduction

C Jiang, AW Nichols, CW Machan - Dalton Transactions, 2019 - pubs.rsc.org
Electrocatalytic CO2 reduction is of continued interest to sustainable energy research.
Mononuclear transition metal complexes from Group 6 to Group 10 with a select subset of …

Chromophore appended DPA-based copper (ii) complexes with a diimine motif towards DNA binding and fragmentation studies

S Mathur, KS Karumban, A Muley, N Tuti… - Dalton …, 2024 - pubs.rsc.org
Mixed ligand copper (II) complexes [Cu (L1)(bpy)](ClO4) 21 and [Cu (L2)(bpy)](ClO4) 22
(where L1= 1-(anthracen-9-yl)-N, N-bis (pyridin-2-ylmethyl) methanamine, L2= 1-(pyren-1 …

Alternating Metal‐Ligand Coordination Improves Electrocatalytic CO2 Reduction by a Mononuclear Ru Catalyst**

H Agarwala, X Chen, JR Lyonnet… - Angewandte …, 2023 - Wiley Online Library
Molecular electrocatalysts for CO2‐to‐CO conversion often operate at large overpotentials,
due to the large barrier for C− O bond cleavage. Illustrated with ruthenium polypyridyl …

Methane Generation from CO2 with a Molecular Rhenium Catalyst

JK Nganga, LM Wolf, K Mullick, E Reinheimer… - Inorganic …, 2021 - ACS Publications
The atomic-level tunability of molecular structures is a compelling reason to develop
homogeneous catalysts for challenging reactions such as the electrochemical reduction of …