Suzuki–Miyaura Cross-Coupling Reactions for Increasing the Efficiency of Tris-Heteroleptic Iridium (III) Emitters

PLT Boudreault, MA Esteruelas, E Mora, E Oñate… - …, 2019 - ACS Publications
The complex Ir (acac){κ2-C, N-[C6BrH3-py]}{κ2-C, N-[C6H4-py]}(2) is a green emitter, which
displays short lifetimes (0.9–4.9 μs) and quantum yields of 0.32 in poly (methyl methacrylate) …

Insertion of unsaturated C–C Bonds into the O–H bond of an Iridium (III)-Hydroxo complex: formation of phosphorescent emitters with an asymmetrical β-Diketonate …

PLT Boudreault, MA Esteruelas, AM López… - Inorganic …, 2020 - ACS Publications
A synthetic methodology to prepare iridium (III) emitters of the class [3b+ 3b+ 3b′] with two
ortho-metalated 1-phenylisoquinolines and an asymmetrical β-diketonate has been …

Transition-metal-catalyzed functionalization of 1, 10-phenanthrolines and their complexes

AS Abel, AD Averin, IP Beletskaya… - Taggets in Heterocyclic …, 2021 - hal.science
1, 10-Phenanthroline is a classical ligand in coordination chemistry which is renowned
among bidentate ligands for the generality of its stable metal complexes widely studied …

Intrinsic hydrogen evolution capability and a theoretically supported reaction mechanism of a paddlewheel-type dirhodium complex

Y Kataoka, N Yano, M Handa, T Kawamoto - Dalton Transactions, 2019 - pubs.rsc.org
The intrinsic capability of the paddlewheel-type dirhodium tetraacetate complex,[Rh2
(O2CCH3) 4 (H2O) 2]([1 (H2O) 2]), as a hydrogen evolution catalyst (HEC) for …

From Molecules to Devices: Effect of Pd-Catalyzed C–H Bond Arylation to Improve Metrics

AA Wayzani, K Zhang, A Benzai, M Cordier… - …, 2024 - ACS Publications
In this study, we detail advancements in the design and application of neutral, arylated,
cyclometalated iridium (III) complexes in the use of OLEDs. We utilized the “catalysis-on-the …

Bromination and C–C Cross-Coupling Reactions for the C–H Functionalization of Iridium (III) Emitters

PLT Boudreault, MA Esteruelas, E Mora, E Onate… - …, 2021 - ACS Publications
The orthometalated phenyl groups of the dimer [Ir (μ-Cl){κ2-C, N-(C6H3Me-py)} 2] 2 have
been selectively brominated, at para-position with regard to the Ir–C bonds, with N …

[HTML][HTML] Novel cyclometalated iridium (III) complexes as antibacterial agents for photodynamic inactivation

M Fallon, R Lalrempuia, L Tabrizi, MP Brandon… - … of Photochemistry and …, 2025 - Elsevier
Staphylococcus aureus and methicillin-resistant S. aureus (MRSA) frequently cause chronic
skin and soft tissue infections and device-related infections. These bacteria colonize human …

Cytotoxic Activities of Bis‐cyclometalated M(III) Complexes (M=Rh, Ir) Containing 5‐substituted 1,10‐Phenanthroline or 4,4'‐substituted 2,2'‐Bipyridine Ligands

M Graf, HC Böttcher, N Metzler‐Nolte… - Zeitschrift für …, 2022 - Wiley Online Library
The synthesis and characterization of eight new bis‐cyclometalated compounds [M (ptpy) 2
(N^ N)] PF6 (ptpy= 2‐(p‐tolyl) pyridinato; N^ N= 5‐chloro‐1, 10‐phenanthroline: M= Rh, 1; …

[HTML][HTML] Luminescent Iridium–Terpyridine Complexes with Various Bis-Cyclometalated Ligands

K Ikeda, N Yano, M Handa, Y Kataoka - Molecules, 2025 - mdpi.com
A series of luminescent bis-cyclometalated iridium complexes with 2, 2′: 6′, 2 ″-
terpyridine (tpy),[Ir (C^ N) 2 (tpy)] PF6 (C^ N= 2-phenylpyridinate (ppy) for 1; benzo [h] …

Palladium‐Catalyzed C− H Bond Arylation of Cyclometalated Difluorinated 2‐Arylisoquinolinyl Iridium (III) Complexes

M Peng, J Lin, W Lu, T Roisnel… - … A European Journal, 2021 - Wiley Online Library
The utility of C− H bond functionalization of metalated ligands for the elaboration of aryl‐
functionalized difluorinated‐1‐arylisoquinolinyl Ir (III) complexes has been explored. Bis [(3 …