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Microstructured gas-liquid-(solid) interfaces: A platform for sustainable synthesis of commodity chemicals
K Wang, M Pera-Titus - Science Advances, 2024 - science.org
Gas-liquid-solid catalytic reactions are widespread in nature and man-made technologies.
Recently, the exceptional reactivity observed on (electro) sprayed microdroplets, in …
Recently, the exceptional reactivity observed on (electro) sprayed microdroplets, in …
Structural Design of Single‐Atom Catalysts for Enhancing Petrochemical Catalytic Reaction Process
M Li, G Sun, Z Wang, X Zhang, J Peng… - Advanced …, 2024 - Wiley Online Library
Petroleum, as the “lifeblood” of industrial development, is the important energy source and
raw material. The selective transformation of petroleum into high‐end chemicals is of great …
raw material. The selective transformation of petroleum into high‐end chemicals is of great …
Water microdroplets in air: a hitherto unnoticed natural source of nitrogen oxides
Water microdroplets are widespread in the atmosphere. We report a striking observation that
micron-sized water droplets obtained from zero-volt spray sources (sonic spray, humidifier …
micron-sized water droplets obtained from zero-volt spray sources (sonic spray, humidifier …
One-step, catalyst-free formation of phenol from benzoic acid using water microdroplets
Benzoic acid dissolved in water is electrosprayed (− 4 kV) by using nitrogen gas at a
pressure of 120 psi to form∼ 10 μm diameter microdroplets. Analysis with mass …
pressure of 120 psi to form∼ 10 μm diameter microdroplets. Analysis with mass …
Valence bond theory allows a generalized description of hydrogen bonding
This paper describes the nature of the hydrogen bond (HB), B:---H–A, using valence bond
theory (VBT). Our analysis shows that the most important HB interactions are polarization …
theory (VBT). Our analysis shows that the most important HB interactions are polarization …
Revisiting the Enhanced Chemical Reactivity in Water Microdroplets: The Case of a Diels–Alder Reaction
Often, chemical reactions are markedly accelerated in microdroplets compared with the
corresponding bulk phase. While identifying the precise causative factors remains …
corresponding bulk phase. While identifying the precise causative factors remains …
Heavy water microdroplet surface enriches the lighter isotopologue impurities
Water microdroplets promote unusual chemical reactions at the air–water interface.
However, the interfacial structure of water microdroplets and its potential influence on …
However, the interfacial structure of water microdroplets and its potential influence on …
Direct Conversion of N2 and Air to Nitric Acid in Gas–Water Microbubbles
We report a simple, direct, and green conversion of air/N2 to nitric acid by bubbling the gas
through an aqueous solution containing 50 μM Fe2+ ions. Air stone, along with …
through an aqueous solution containing 50 μM Fe2+ ions. Air stone, along with …
My vision of electric-field-aided chemistry in 2050
S Shaik - ACS Physical Chemistry Au, 2024 - ACS Publications
This manuscript outlines my outlook on the development of electric-field (EF)-mediated-
chemistry and the vision of its state by 2050. I discuss applications of oriented-external …
chemistry and the vision of its state by 2050. I discuss applications of oriented-external …
Identification of the Electrogenerated Hidden Nitrenium Ions by In Situ Mass Spectrometry
CY Liu, Y Chen, J Hu - Analytical Chemistry, 2024 - ACS Publications
The identification of the electrogenerated reactive intermediates is essential for an in-depth
understanding of the electroredox processes. Although various short-lived intermediates are …
understanding of the electroredox processes. Although various short-lived intermediates are …