My vision of electric-field-aided chemistry in 2050

S Shaik - ACS Physical Chemistry Au, 2024 - ACS Publications
This manuscript outlines my outlook on the development of electric-field (EF)-mediated-
chemistry and the vision of its state by 2050. I discuss applications of oriented-external …

Valence bond theory allows a generalized description of hydrogen bonding

S Shaik, D Danovich, RN Zare - Journal of the American Chemical …, 2023 - ACS Publications
This paper describes the nature of the hydrogen bond (HB), B:---H–A, using valence bond
theory (VBT). Our analysis shows that the most important HB interactions are polarization …

Utilization of Electric Fields to Modulate Molecular Activities on the Nanoscale: From Physical Properties to Chemical Reactions

C Yang, Y Guo, H Zhang, X Guo - Chemical Reviews, 2024 - ACS Publications
As a primary energy source, electricity drives broad fields from everyday electronic circuits to
industrial chemical catalysis. From a chemistry viewpoint, studying electric field effects on …

One-step, catalyst-free formation of phenol from benzoic acid using water microdroplets

Y Meng, RN Zare, E Gnanamani - Journal of the American …, 2023 - ACS Publications
Benzoic acid dissolved in water is electrosprayed (− 4 kV) by using nitrogen gas at a
pressure of 120 psi to form∼ 10 μm diameter microdroplets. Analysis with mass …

Heavy water microdroplet surface enriches the lighter isotopologue impurities

A Nandy, S Mondal, D Koner… - Journal of the American …, 2024 - ACS Publications
Water microdroplets promote unusual chemical reactions at the air–water interface.
However, the interfacial structure of water microdroplets and its potential influence on …

Direct Conversion of N2 and Air to Nitric Acid in Gas–Water Microbubbles

S Bose, M Mofidfar, RN Zare - Journal of the American Chemical …, 2024 - ACS Publications
We report a simple, direct, and green conversion of air/N2 to nitric acid by bubbling the gas
through an aqueous solution containing 50 μM Fe2+ ions. Air stone, along with …

Revisiting the Enhanced Chemical Reactivity in Water Microdroplets: The Case of a Diels–Alder Reaction

K Gong, A Nandy, Z Song, QS Li… - Journal of the …, 2024 - ACS Publications
Often, chemical reactions are markedly accelerated in microdroplets compared with the
corresponding bulk phase. While identifying the precise causative factors remains …

Identification of the Electrogenerated Hidden Nitrenium Ions by In Situ Mass Spectrometry

CY Liu, Y Chen, J Hu - Analytical Chemistry, 2024 - ACS Publications
The identification of the electrogenerated reactive intermediates is essential for an in-depth
understanding of the electroredox processes. Although various short-lived intermediates are …

Structural Design of Single‐Atom Catalysts for Enhancing Petrochemical Catalytic Reaction Process

M Li, G Sun, Z Wang, X Zhang, J Peng… - Advanced …, 2024 - Wiley Online Library
Petroleum, as the “lifeblood” of industrial development, is the important energy source and
raw material. The selective transformation of petroleum into high‐end chemicals is of great …

Microstructured gas-liquid-(solid) interfaces: A platform for sustainable synthesis of commodity chemicals

K Wang, M Pera-Titus - Science Advances, 2024 - science.org
Gas-liquid-solid catalytic reactions are widespread in nature and man-made technologies.
Recently, the exceptional reactivity observed on (electro) sprayed microdroplets, in …