Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

State of the art and prospects in metal–organic framework (MOF)-based and MOF-derived nanocatalysis

Q Wang, D Astruc - Chemical reviews, 2019 - ACS Publications
Metal–organic framework (MOF) nanoparticles, also called porous coordination polymers,
are a major part of nanomaterials science, and their role in catalysis is becoming central …

Limits of detection for EXAFS characterization of heterogeneous single-atom catalysts

J Finzel, KM Sanroman Gutierrez, AS Hoffman… - ACS …, 2023 - ACS Publications
Single-atom catalysts (SACs), consisting of individual metal atoms dispersed on a support,
attract attention due to their unique reactivity, efficient use of precious metals, and precise …

Introduction: nanoparticles in catalysis

D Astruc - Chemical reviews, 2020 - ACS Publications
Decreasing the nanocatalyst size down to single atom 20− 22 has attracted much recent
attention, because in this case no atoms located at the interior of the nanoparticle are lost …

First-generation organic reaction intermediates in zeolite chemistry and catalysis

X Gong, M Caglayan, Y Ye, K Liu, J Gascon… - Chemical …, 2022 - ACS Publications
Zeolite chemistry and catalysis are expected to play a decisive role in the next decade (s) to
build a more decentralized renewable feedstock-dependent sustainable society owing to the …

Single-atom catalysis: Insights from model systems

F Kraushofer, GS Parkinson - Chemical Reviews, 2022 - ACS Publications
The field of single-atom catalysis (SAC) has expanded greatly in recent years. While there
has been much success develo** new synthesis methods, a fundamental disconnect …

The comparison between single atom catalysis and surface organometallic catalysis

MK Samantaray, V D'Elia, E Pump, L Falivene… - Chemical …, 2019 - ACS Publications
Single atom catalysis (SAC) is a recent discipline of heterogeneous catalysis for which a
single atom on a surface is able to carry out various catalytic reactions. A kind of revolution …

Engineering single-atom catalysts toward biomedical applications

B Chang, L Zhang, S Wu, Z Sun, Z Cheng - Chemical Society Reviews, 2022 - pubs.rsc.org
Due to inherent structural defects, common nanocatalysts always display limited catalytic
activity and selectivity, making it practically difficult for them to replace natural enzymes in a …

Design and Advanced Manufacturing of NU‐1000 Metal–Organic Frameworks with Future Perspectives for Environmental and Renewable Energy Applications

R Abazari, S Sanati, MA Bajaber, MS Javed, PC Junk… - Small, 2024 - Wiley Online Library
Metal–organic frameworks (MOFs) represent a relatively new family of materials that attract
lots of attention thanks to their unique features such as hierarchical porosity, active metal …

Modeling Single‐Atom Catalysis

G Di Liberto, G Pacchioni - Advanced Materials, 2023 - Wiley Online Library
Electronic structure calculations represent an essential complement of experiments to
characterize single‐atom catalysts (SACs), consisting of isolated metal atoms stabilized on a …