Transition metal catalysts for controlled radical polymerization
The discovery, in the mid 1990s, that certain cobalt, ruthenium and copper complexes could
effectively control the radical polymerization of a number of polar olefins, allowing for the …
effectively control the radical polymerization of a number of polar olefins, allowing for the …
Organocobalt complexes as sources of carbon-centered radicals for organic and polymer chemistries
Organocobalt (III) complexes (R-CoIII), defined as cobalt complexes featuring a carbon–
cobalt bond, are largely used to produce carbon-centered radicals by homolytic cleavage of …
cobalt bond, are largely used to produce carbon-centered radicals by homolytic cleavage of …
Overview of cobalt-mediated radical polymerization: Roots, state of the art and future prospects
Controlled radical polymerization (CRP) techniques offer the opportunity to properly design
polymer chains and adjust their chemical and physical properties. Among these techniques …
polymer chains and adjust their chemical and physical properties. Among these techniques …
Organometallic mediated radical polymerization
LEN Allan, MR Perry, MP Shaver - Progress in polymer science, 2012 - Elsevier
Controlled radical polymerization has become increasingly important over the past decade
and a half, allowing for the facile synthesis of specific macromolecular architectures with …
and a half, allowing for the facile synthesis of specific macromolecular architectures with …
Robust UV-cured superhydrophobic cotton fabric surfaces with self-healing ability
For extending the lifespan of practical applications, a robust and self-healing
superhydrophobic cotton fabric was successfully fabricated by facile dip coating and UV …
superhydrophobic cotton fabric was successfully fabricated by facile dip coating and UV …
Controlled cobalt-mediated free-radical co-and terpolymerization of carbon monoxide
A Fuchs, S Mecking - Journal of the American Chemical Society, 2022 - ACS Publications
While controlled free-radical polymerizations are established for a vast range of vinyl
monomers, they have not been reported for carbon monoxide, although it is a unique …
monomers, they have not been reported for carbon monoxide, although it is a unique …
Iron-mediated reversible deactivation controlled radical polymerization
Metal-mediated reversible deactivation radical polymerization (RDRP) is now a cornerstone
of functional polymer synthesis, dominated by copper complexes and the Atom Transfer …
of functional polymer synthesis, dominated by copper complexes and the Atom Transfer …
Insight into organometallic-mediated radical polymerization
M Hurtgen, C Detrembleur, C Jerome… - Polymer Reviews, 2011 - Taylor & Francis
This review focuses on an emerging class of controlled radical polymerization named
Organometallic-Mediated Radical Polymerization (OMRP). The latter is based on the …
Organometallic-Mediated Radical Polymerization (OMRP). The latter is based on the …
Mechanistic Insights into the Cobalt‐Mediated Radical Polymerization (CMRP) of Vinyl Acetate with Cobalt (III) Adducts as Initiators
Over the past few years, cobalt‐mediated radical polymerization (CMRP) has proved
efficient in controlling the radical polymerization of very reactive monomers, such as vinyl …
efficient in controlling the radical polymerization of very reactive monomers, such as vinyl …
Cobalt-catalyzed trifluoromethylation–peroxidation of unactivated alkenes with sodium trifluoromethanesulfinate and hydroperoxide
HY Zhang, C Ge, J Zhao, Y Zhang - Organic letters, 2017 - ACS Publications
Disclosed herein is an unprecedented cobalt-catalyzed trifluoromethylation–peroxidation of
unactivated alkenes. In this process the hydroperoxide acts as a radical initiator as well as a …
unactivated alkenes. In this process the hydroperoxide acts as a radical initiator as well as a …