Understanding the unceasing evolution of Co (II) based single-ion magnets

PK Sahu, R Kharel, S Shome, S Goswami… - Coordination Chemistry …, 2023 - Elsevier
Single-molecule magnets (SMMs) are molecules that exhibit energy barriers to spin
inversion. The slow relaxation of magnetization is of molecular origin and arises from the …

3d single-ion magnets

GA Craig, M Murrie - Chemical Society Reviews, 2015 - pubs.rsc.org
One of the determining factors in whether single-molecule magnets (SMMs) may be used as
the smallest component of data storage, is the size of the barrier to reversal of the …

The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

JM Frost, KLM Harriman, M Murugesu - Chemical science, 2016 - pubs.rsc.org
Single-molecule magnets (SMMs) that contain one spin centre (so-called single-ion
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …

A four-coordinate cobalt (II) single-ion magnet with coercivity and a very high energy barrier

Y Rechkemmer, FD Breitgoff, M Van Der Meer… - Nature …, 2016 - nature.com
Single-molecule magnets display magnetic bistability of molecular origin, which may one
day be exploited in magnetic data storage devices. Recently it was realised that increasing …

Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

AK Bar, C Pichon, JP Sutter - Coordination Chemistry Reviews, 2016 - Elsevier
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

Large magnetic anisotropy in mononuclear metal complexes

S Gómez-Coca, D Aravena, R Morales… - Coordination Chemistry …, 2015 - Elsevier
This review examines mononuclear metal complexes with high magnetic anisotropy and the
theoretical approaches used to rationalize their magnetic properties. Electronic structure …

Computational design of magnetic molecules and their environment using quantum chemistry, machine learning and multiscale simulations

A Lunghi, S Sanvito - Nature Reviews Chemistry, 2022 - nature.com
Having served as a playground for fundamental studies on the physics of d and f electrons
for almost a century, magnetic molecules are now becoming increasingly important for …

Main group chemistry at the interface with molecular magnetism

FS Guo, AK Bar, RA Layfield - Chemical reviews, 2019 - ACS Publications
Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …

Unraveling the contributions to spin–lattice relaxation in kramers single-molecule magnets

S Mondal, A Lunghi - Journal of the American Chemical Society, 2022 - ACS Publications
The study of how spin interacts with lattice vibrations and relaxes to equilibrium provides
unique insights into its chemical environment and the relation between electronic structure …

Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical Communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …