Precise Control of π-electron Magnetism in Metal-free Porphyrins

Y Zhao, K Jiang, C Li, Y Liu, C Xu… - Journal of the …, 2020 - ACS Publications
The porphyrin macrocycle can stabilize a set of magnetic metal ions, thus introducing
localized net spins near the center. However, it remains elusive but most desirable to …

Do Corroles Stabilize Tetravalent Antimony?

S Eulberg, N Schulze, J Krumsieck… - Angewandte Chemie …, 2023 - Wiley Online Library
Antimony corrole cations have been prepared by one‐electron oxidation of antimony (III)
congeners with silver (I) and copper (II) salts. Isolation and crystallization was successful for …

Minding our P-block and Q-bands: paving inroads into main group corrole research to help instil broader potential

W Lee, X Zhan, J Palma, J Vestfrid, Z Gross… - Chemical …, 2021 - pubs.rsc.org
Main group chemistry is often considered less “dynamic” than transition metal (TM)
chemistry because of predictable VSEPR-based central atom geometries, relatively slower …

Antiaromaticity-promoted radical stability in α-methyl heterocyclics

L Lin, J Zhu - The Journal of Organic Chemistry, 2021 - ACS Publications
Aromaticity is a fundamental and important concept in chemistry, and usually, the
enhancement of aromaticity brings additional thermodynamic stability to a compound …

Deciphering electronic and structural effects in Copper Corrole/Graphene Hybrids

K Wrighton‐Araneda… - … A European Journal, 2023 - Wiley Online Library
Non‐covalent hybrid materials based on graphene and A3‐type copper corrole complexes
were computationally investigated. The corroles complexes contain strong electron …

Why can cobalt (III) corrole form more stable metal/organic interfaces than cobalt (II) porphyrin?

J Herritsch, M Zugermeier, M Schmid… - Journal of Porphyrins …, 2023 - World Scientific
The ring size of tetrapyrrole ligands can dramatically influence the interfacial interactions of
their metal complexes, as was found in a comparison of alkyl-substituted cobalt (II) …

CoIIIcorrole: versatile synthetic methods and wide range of applications

T Gu, Z Zhang, S Zhang, W Zhu, X Liang - Journal of Inclusion …, 2022 - Springer
This review introduces the synthesis, properties and applications of CoIIIcorroles. The
synthesis methods are containing A2B type, A3 type, ABC type, Hangman H3corrole and …

Chemical and Physical Properties of Single Molecules and Their Assemblies Adsorbed on Solid Surfaces

V Houska - 2023 - dspace.cuni.cz
Interaction of organic molecules with solid surfaces represents a key area of physical-
chemistry research. From heterogenous catalysis to OLED displays, in numerous such …

Augmented Magnetic Response and Spin-Transfer in Copper Corrole/Graphene Hybrids-A DFT Study

The search for hybrid materials with outstanding electronic performance is highly
demanding Since copper corroles have emerged as versatile building blocks providing …

Reactivity of organic molecules on semiconductor surfaces revealed by density functional theory

F Pieck, JN Luy, F Kreuter, B Mondal… - … Conference on High …, 2021 - Springer
The present report discusses the reactivity and properties of organic molecules on mainly
semiconductor surfaces by means of density functional theory. For pyrazine on Ge (001), a …