Transition‐metal‐catalyzed C− H functionalization reactions with Cp* MIII catalysts (M= Co,
Rh, Ir) have found a wide variety of applications in organic synthesis. Albeit the intrinsic …

Hydrofunctionalization of alkenes and alkynes is increasingly important in preparing and
modifying carbon-centered organic molecules such as pharmaceuticals, agrochemicals, and …

Deoxy‐β‐C‐glycosides represent an important class of carbohydrates that are present in
many bioactive molecules. However, owing to the lack of substituents at the C2 position, the …

Enantioselective C–H oxidation is a standing chemical challenge foreseen as a powerful
tool to transform readily available organic molecules into precious oxygenated building …

Great efforts have been directed toward alkene π bond amination. In contrast, analogous
functionalization of the adjacent C (sp3)–C (sp2) σ bonds is much rarer. Here we report how …

Petroleum, as the “lifeblood” of industrial development, is the important energy source and
raw material. The selective transformation of petroleum into high‐end chemicals is of great …

The isomerization of 1, 1-disubstituted alkenes through 1, 3-hydrogen shift is an atom-
efficient route for synthesizing trisubstituted alkenes, which are important moieties in many …

Asymmetric hydrogenation finds widespread application in academia and industry. And
indeed, a number of processes have been implemented for the production of pharma and …

Transition metal catalyzed alkene double bond transposition usually involves metal hydride
intermediates. Despite significant advances in the design of catalysts that dictate product …

While Mn-catalyzed (de) hydrogenation of carbonyl derivatives has been well established,
the reactivity of Mn hydrides with olefins remains very rare. Herein, we report a Mn (I) pincer …