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Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …
anisotropy of mono-nuclear transition metal complexes in various coordination …
Molecular magnetic materials based on 4d and 5d transition metals
The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …
research topic in the field of molecular magnetism. An essential driving force for the interest …
Slow magnetization dynamics in a series of two-coordinate iron (II) complexes
A series of two-coordinate complexes of iron (II) were prepared and studied for single-
molecule magnet behavior. Five of the compounds, Fe [N (SiMe3)(Dipp)] 2 (1), Fe [C …
molecule magnet behavior. Five of the compounds, Fe [N (SiMe3)(Dipp)] 2 (1), Fe [C …
Single-molecule magnet engineering: building-block approaches
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …
the constituent metal ion building blocks. Although this general approach does not seem to …
A promising new route towards single-molecule magnets based on the oxalate ligand
A unique purely lanthanide-based single-molecule magnet (SMM) with an oxalate bridge
has been designed through a rational synthetic approach. This strategy opens up new …
has been designed through a rational synthetic approach. This strategy opens up new …
[ReCl4(CN)2]2−: A High Magnetic Anisotropy Building Unit Giving Rise to the Single-Chain Magnets (DMF)4MReCl4(CN)2 (M = Mn, Fe, Co, Ni)
An S= 3/2, high-anisotropy building unit, trans-[ReCl4 (CN) 2] 2−, representing the first
paramagnetic complex with a mixture of just cyanide and halide ligands, has been …
paramagnetic complex with a mixture of just cyanide and halide ligands, has been …
Cluster-based single-molecule magnets
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …
2005 but also including coverage of earlier work where necessary for understanding of …
Trinuclear Heterobimetallic Ni2Ln complexes [L2Ni2Ln][ClO4](Ln= La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Er; LH3=(S) P [N (Me) N CH− C6H3-2-OH-3-OMe] 3) …
The reaction of LH3 with Ni (ClO4) 2· 6H2O and lanthanide salts in a 2: 2: 1 ratio in the
presence of triethylamine leads to the formation of the trinuclear complexes …
presence of triethylamine leads to the formation of the trinuclear complexes …
Synthesis, Structure, and Magnetism of Heterobimetallic Trinuclear Complexes {[L2Co2Ln][X]} [Ln = Eu, X = Cl; Ln = Tb, Dy, Ho, X = NO3; LH3 = (S)P[N(Me)NCH−C6H3-2 …
Sequential reaction of LH3 (LH3=(S) P [N (Me) N CH− C6H3-2-OH-3-OMe] 3) with Co
(OAc) 2· 4H2O followed by reaction with lanthanide salts afforded trinuclear heterobimetalllic …
(OAc) 2· 4H2O followed by reaction with lanthanide salts afforded trinuclear heterobimetalllic …
[ReF6]2−: A Robust Module for the Design of Molecule‐Based Magnetic Materials
A facile synthesis of the [ReF6] 2− ion and its use as a building block to synthesize magnetic
systems are reported. Using dc and ac magnetic susceptibility measurements, INS and EPR …
systems are reported. Using dc and ac magnetic susceptibility measurements, INS and EPR …