Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020 - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …

Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization

X Wang, J He, YN Wang, Z Zhao, K Jiang… - Chemical …, 2024 - ACS Publications
Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Toward green atom transfer radical polymerization: current status and future challenges

S Dworakowska, F Lorandi, A Gorczyński… - Advanced …, 2022 - Wiley Online Library
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …

Ultrafast visible-light-induced ATRP in aqueous media with carbon quantum dots as the catalyst and its application for 3D printing

L Qiao, M Zhou, G Shi, Z Cui, X Zhang… - Journal of the …, 2022 - ACS Publications
Photoinduced atom transfer radical polymerization (ATRP) has been proved to be a versatile
technique for polymer network formation. However, the slow polymerization rates of typical …

Current status and outlook for ATRP

K Matyjaszewski - European Polymer Journal, 2024 - Elsevier
Atom transfer radical polymerization (ATRP) is one of the most often used controlled radical
polymerization techniques. It employs very small amounts (ppm) of Cu complexes in the …

Radical photoinitiation with LEDs and applications in the 3D printing of composites

Y Zhang, Y Xu, A Simon-Masseron… - Chemical Society …, 2021 - pubs.rsc.org
Radical initiation upon LED light irradiation is discussed herein as well as its application in
additive manufacturing. The ability of manufacturing complex structures, freedom of design …

Emerging trends in development and application of 3D printed nanocomposite polymers for sustainable environmental solutions

S Siddiqui, S Surananai, K Sainath, MZ Khan… - European Polymer …, 2023 - Elsevier
Additive manufacturing (AM) technology has revolutionized the way we produce three-
dimensional (3D) objects, enabling the creation of intricate, custom designs with distinctive …

Reversible deactivation radical polymerization: from polymer network synthesis to 3D printing

A Bagheri, CM Fellows, C Boyer - Advanced Science, 2021 - Wiley Online Library
Abstract 3D printing has changed the fabrication of advanced materials as it can provide
customized and on‐demand 3D networks. However, 3D printing of polymer materials with …

A Photoinduced Dual‐Wavelength Approach for 3D Printing and Self‐Healing of Thermosetting Materials

Z Zhang, N Corrigan, C Boyer - Angewandte Chemie, 2022 - Wiley Online Library
Vat photopolymerization‐based 3D printing techniques have been widely used to produce
high‐resolution 3D thermosetting materials. However, the lack of repairability of these …

Application of RAFT in 3D printing: where are the future opportunities?

A Bagheri - Macromolecules, 2023 - ACS Publications
Research into 3D printing using reversible addition–fragmentation chain transfer (RAFT)
polymerization has garnered interest since it was first reported in 2019. This technique was …