Regulation of the Si/Al ratios and Al distributions of zeolites and their impact on properties

J Li, M Gao, W Yan, J Yu - Chemical Science, 2023 - pubs.rsc.org
Zeolites are typically a class of crystalline microporous aluminosilicates that are constructed
by SiO4 and AlO4 tetrahedra. Because of their unique porous structures, strong Brönsted …

Small-pore zeolites: synthesis and catalysis

M Dusselier, ME Davis - Chemical reviews, 2018 - ACS Publications
In the past decade or so, small-pore zeolites have received greater attention than large-and
medium-pore molecular sieves that have historically dominated the literature. This is …

Engineering of transition metal catalysts confined in zeolites

N Kosinov, C Liu, EJM Hensen, EA Pidko - Chemistry of Materials, 2018 - ACS Publications
Transition metal–zeolite composites are versatile catalytic materials for a wide range of
industrial and lab-scale processes. Significant advances in fabrication and characterization …

Analysis and control of acid sites in zeolites

A Palčić, V Valtchev - Applied Catalysis A: General, 2020 - Elsevier
The exceptional catalytic performance of zeolites is due to the presence of active sites in a
shape-selective environment, ie, in micropores with molecular dimensions. The present …

Tuning the aluminum distribution in zeolites to increase their performance in acid‐catalyzed reactions

J Dědeček, E Tabor, S Sklenak - ChemSusChem, 2019 - Wiley Online Library
The organization of Al atoms in the framework of Si‐rich zeolites is very important and
includes two classes:(i) the Al siting that determines which individual, crystallographically …

Recent progress in the improvement of hydrothermal stability of zeolites

R Simancas, A Chokkalingam, SP Elangovan, Z Liu… - Chemical …, 2021 - pubs.rsc.org
Zeolites have been successfully employed in many catalytic reactions of industrial
relevance. The severe conditions required in some processes, where high temperatures are …

Fe-MOR and Fe-FER as catalysts for abatement of N2O with CH4: in situ UV–vis DRS and operando FTIR study

MC Campa, D Pietrogiacomi, C Catracchia… - Applied Catalysis B …, 2024 - Elsevier
The catalytic reduction of N 2 O with CH 4 in absence or in presence of O 2 (CR N2O or SCR
N2O) and H 2 O (hydrothermal conditions) was studied on Fe-MOR and Fe-FER catalysts …

Al organization in the SSZ-13 zeolite. Al distribution and extraframework sites of divalent cations

K Mlekodaj, J Dedecek, V Pashkova… - The Journal of …, 2018 - ACS Publications
SSZ-13 is a Si-rich (Si/Al> 5) small pore zeolite (chabazite topology) important for both acid
and redox catalysis. Using a sample with Si/Al= 12, a new procedure involving 27Al (3Q) …

Understanding deNO x mechanisms in transition metal exchanged zeolites

JA Nasir, AM Beale, CRA Catlow - Chemical Society Reviews, 2024 - pubs.rsc.org
Transition-metal-containing zeolites have wide-ranging applications in several catalytic
processes including the selective catalytic reduction (SCR) of NOx species. To understand …

Energy analysis of aluminosilicate zeolites with comprehensive ranges of framework topologies, chemical compositions, and aluminum distributions

K Muraoka, W Chaikittisilp, T Okubo - Journal of the American …, 2016 - ACS Publications
The contents and locations of Al in the zeolite frameworks are one of the key factors
determining the physicochemical properties of zeolites. Systematic evaluation of the …