The Role of In Situ/Operando IR Spectroscopy in Unraveling Adsorbate-Induced Structural Changes in Heterogeneous Catalysis

E Groppo, S Rojas-Buzo, S Bordiga - Chemical Reviews, 2023 - ACS Publications
Heterogeneous catalysts undergo thermal-and/or adsorbate-induced dynamic changes
under reaction conditions, which consequently modify their catalytic behavior. Hence, it is …

Metal-organic frameworks for photocatalytic CO2 reduction under visible radiation: A review of strategies and applications

II Alkhatib, C Garlisi, M Pagliaro, K Al-Ali, G Palmisano - Catalysis Today, 2020 - Elsevier
Metal-organic frameworks (MOFs) have emerged over the last decades as an interesting
class of materials for a plethora of applications due to their flexible tunability in composition …

Fe-Based MOFs for Photocatalytic CO2 Reduction: Role of Coordination Unsaturated Sites and Dual Excitation Pathways

D Wang, R Huang, W Liu, D Sun, Z Li - Acs Catalysis, 2014 - ACS Publications
The utilization of solar energy for the conversion of CO2 into valuable organic products is
one of the best solutions to solve the problems of global warming and energy shortage. The …

Synthesis, characterization and application of Fe-zeolite: A review

J Zhang, X Tang, H Yi, Q Yu, Y Zhang, J Wei… - Applied Catalysis A …, 2022 - Elsevier
Fe-zeolites are widely applied in petrochemical, fine chemical, environmental protection,
and other catalytic fields because of the zeolitic properties as well as the redox properties …

Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques

S Bordiga, E Groppo, G Agostini… - Chemical …, 2013 - ACS Publications
Starting from the late seventies, the progressively increased availability of synchrotron light
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …

[PDF][PDF] Direct catalytic conversion of methane to methanol in an aqueous medium by using copper‐promoted Fe‐ZSM‐5

C Hammond, MM Forde, MH Ab Rahim… - Angewandte Chemie …, 2012 - academia.edu
The selective oxidation of primary carbon–hydrogen bonds is of crucial importance in
activating raw materials to form intermediates and final products for use in the chemical …

Solvent-free synthesis of zeolites from solid raw materials

L Ren, Q Wu, C Yang, L Zhu, C Li… - Journal of the …, 2012 - ACS Publications
As important industrial materials, microporous zeolites are necessarily synthesized in the
presence of solvents such as in hydrothermal, solvothermal, and ionothermal routes. We …

Assignment of pre‐edge peaks in K‐edge x‐ray absorption spectra of 3d transition metal compounds: Electric dipole or quadrupole?

T Yamamoto - X‐Ray Spectrometry: An International Journal, 2008 - Wiley Online Library
The characteristics of pre‐edge peaks in K‐edge x‐ray absorption near edge structure
(XANES) spectra of 3d transition metals were reviewed from viewpoints of the selection rule …

Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy

C Lamberti, A Zecchina, E Groppo… - Chemical Society …, 2010 - pubs.rsc.org
This critical review describes the reactivity of heterogeneous catalysts from the point of view
of four simple, but essential for Chemistry, molecules (namely dihydrogen, carbon …

Maximizing active Fe species in ZSM-5 zeolite using organic-template-free synthesis for efficient selective methane oxidation

Q Cheng, G Li, X Yao, L Zheng, J Wang… - Journal of the …, 2023 - ACS Publications
The selective oxidation of CH4 in the aqueous phase to produce valuable chemicals has
attracted considerable attention due to its mild reaction conditions and simple process. As …